[(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane

Base Information

Chemical Name:[(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane
CAS No.:54006-28-9
Molecular Formula:C25H22P2S
Molecular Weight:416.463
Hs Code.:
NSC Number:193721
DSSTox Substance ID:DTXSID40307666
Nikkaji Number:J1.111.192K
Wikidata:Q82055161

Synonyms:54006-28-9;NSC193721;SCHEMBL8719329;DTXSID40307666;[(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane;NSC-193721

Suppliers and Price of [(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of [(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane

Chemical Property:

Vapor Pressure:2.9E-11mmHg at 25°C
Boiling Point:542.1°C at 760 mmHg
Flash Point:281.6°C
XLogP3:7.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:416.09174587
Heavy Atom Count:28
Complexity:455

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CP(=S)(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of [(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane

There total 11 articles about [(Diphenylphosphanyl)methyl](diphenyl)sulfanylidene-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 13639-74-2
methyldiphenylphosphine sulfide

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 54006-28-9
(diphenylphosphinomethyl)diphenylphosphine sulphide

Guidance literature:: methyldiphenylphosphine sulfide; With n-butyllithium; In tetrahydrofuran; at -78 ℃;

chloro-diphenylphosphine; In tetrahydrofuran;
DOI:10.1002/open.202100187

Reference yield: 52.0%

: 2071-20-7
bis-diphenylphosphinomethane

: 14633-92-2
bis(diphenylthiophosphoryl)methane

: 54006-28-9
(diphenylphosphinomethyl)diphenylphosphine sulphide

Guidance literature:: With sulfur; In neat (no solvent); for 4h; Milling; Green chemistry;
DOI:10.1002/ejic.201701414

Reference yield: 41.2%

: 870196-78-4
tetrakis(dimethylamido)hafnium(IV)

: 14633-92-2
bis(diphenylthiophosphoryl)methane

: (1,3-C₆H₄((C₆H₅)PS)₂)CH₂

: [1,3-C₆H₄((C₆H₅)PS)((C₆H₅)P)CH₂]

: [1,3-C₆H₄((C₆H₅)PS)₂C(S)]₂Hf

: 54006-28-9
(diphenylphosphinomethyl)diphenylphosphine sulphide

Guidance literature:: tetrakis(dimethylamido)hafnium(IV); bis(diphenylthiophosphoryl)methane; (1,3-C₆H₄((C₆H₅)PS)₂)CH₂; In toluene; at 20 ℃; Inert atmosphere; Schlenk technique;

In toluene; at 140 ℃; Sealed tube; Reflux;
DOI:10.1039/c5dt01212k