[IrCl(bis(diphenylphosphino)methane)2]

Base Information

Chemical Name:[IrCl(bis(diphenylphosphino)methane)2]
CAS No.:132939-91-4
Molecular Formula:C₅₀H₄₄ClIrP₄
Molecular Weight:996.467
Hs Code.:

Synonyms:[IrCl(bis(diphenylphosphino)methane)2]

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Chemical Property of [IrCl(bis(diphenylphosphino)methane)2]

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Technology Process of [IrCl(bis(diphenylphosphino)methane)2]

There total 2 articles about [IrCl(bis(diphenylphosphino)methane)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: diμ-chlorotetrakis(η2-cyclooctene)diiridium(I)

: 2071-20-7
bis-diphenylphosphinomethane

: 132939-91-4
[IrCl(bis(diphenylphosphino)methane)2]

Guidance literature:: In benzene; (Ar); stirred for 1 h; evapd. (vac.); dissolved in CH2Cl2; cooled to -18°C; elem. anal.;
DOI:10.1021/om00051a018

Reference yield:

: chloro(1,1-bis(diphenylphosphino)methane)(1,1-bis(diphenylphosphino)methanido)hydridoiridium(III)

: 132939-91-4
[IrCl(bis(diphenylphosphino)methane)2]

Guidance literature:: In dichloromethane; (Ar); std. Schlenk technique; soln. of Ir complex in CH2Cl2 was kept at room temp.; NMR monitoring;
DOI:10.1021/om049142i

Reference yield: 81.0%

: 119207-87-3
[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Re(CO)5]

: 132939-91-4
[IrCl(bis(diphenylphosphino)methane)2]

: {IrRe(CO)5(dppm)2}

Guidance literature:: With CO; In tetrahydrofuran; byproducts: Ph2PNPPh2Cl; (Ar), solns. of educts (mole ratio 1:1) stirred for 22 h; removal of PPNCl ppt. on addn. of Et2O; evapn. of solvent in vac.; addn. of CH2Cl2; passing CO through soln. for 15 min with stirring; pptn. on stirring with of hexane; washing with Et2O (five times), elem. anal.;
DOI:10.1021/om00053a020