(Z)-Si,Si-diphenyl-5-silacycloheptene

Base Information

• Chemical Name: (Z)-Si,Si-diphenyl-5-silacycloheptene
• CAS No.: 51051-60-6
• Molecular Formula: C₁₈H₂₀Si
• Molecular Weight: 264.442
• Mol file: 51051-60-6.mol

Synonyms:(Z)-Si,Si-diphenyl-5-silacycloheptene

Chemical Property of (Z)-Si,Si-diphenyl-5-silacycloheptene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-Si,Si-diphenyl-5-silacycloheptene

There total 9 articles about (Z)-Si,Si-diphenyl-5-silacycloheptene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

di(but-3-en-1-yl)diphenylsilane → (Z)-Si,Si-diphenyl-5-silacycloheptene (51051-60-6)

Guidance literature:

With Grubbs catalyst first generation; In dichloromethane; for 1h; Inert atmosphere; Reflux;

Reference yield:

5,5-diphenyl-[1,5]thiasilocane 1,1-dioxide (51051-59-3) → (Z)-Si,Si-diphenyl-5-silacycloheptene (51051-60-6)

Guidance literature:

With potassium hydroxide; tert-butyl alcohol; In tetrachloromethane;

DOI:10.1021/jo00924a019

Reference yield:

diallyldiphenylsilane (10519-88-7) → (Z)-Si,Si-diphenyl-5-silacycloheptene (51051-60-6)

Guidance literature:

Multi-step reaction with 3 steps

1: H₂S / pentane / Irradiation

2: MCPBA / CH₂Cl₂

3: KOH, tBuOH / CCl₄

With potassium hydroxide; hydrogen sulfide; 3-chloro-benzenecarboperoxoic acid; tert-butyl alcohol; In tetrachloromethane; dichloromethane; pentane;

DOI:10.1021/jo00924a019

upstream raw materials:

1,1-diphenyl-silepane-4,5-diol

5,5-diphenyl-[1,5]thiasilocane 1,1-dioxide

3,3'-diphenylsilanediyl-bis-propionic acid dimethyl ester

diallyldiphenylsilane