(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

Base Information

Chemical Name:(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol
CAS No.:862603-57-4
Molecular Formula:C₂₉H₃₆O₄Si
Molecular Weight:476.688
Hs Code.:

Synonyms:(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

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Chemical Property of (S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

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Technology Process of (S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

There total 6 articles about (S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 862603-54-1
(3S,4S)-6-(tert-Butyl-diphenyl-silanyloxy)-hexane-1,3,4-triol

: 1125-88-8
benzaldehyde dimethyl acetal

: 862603-57-4
(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ja0526867

Reference yield:

: 862603-51-8
6-(tert-butyl-diphenyl-silanyloxy)-hex-3-enoic acid methyl ester

: 862603-57-4
(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

Guidance literature:: Multi-step reaction with 3 steps

1: AD-mix-α; methanesulfonamide / 2-methyl-propan-2-ol; H2O / 20 h / 0 °C

2: LiAlH₄ / tetrahydrofuran / -78 - 20 °C

3: (+/-)-camphorsulfonic acid / CH₂Cl₂ / 1 h / 20 °C

With AD-mix-α; lithium aluminium tetrahydride; methanesulfonamide; camphor-10-sulfonic acid; In tetrahydrofuran; dichloromethane; water; tert-butyl alcohol; 1: Sharpless asymmetric dihydroxylation;
DOI:10.1021/ja0526867

Reference yield:

: 862602-87-7
(4S,5S)-5-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4-hydroxy-dihydro-furan-2-one

: 862603-57-4
(S)-3-(tert-Butyl-diphenyl-silanyloxy)-1-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-propan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / tetrahydrofuran / -78 - 20 °C

2: (+/-)-camphorsulfonic acid / CH₂Cl₂ / 1 h / 20 °C

With lithium aluminium tetrahydride; camphor-10-sulfonic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja0526867