2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

Base Information

Chemical Name:2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran
CAS No.:85354-58-1
Molecular Formula:C₂₇H₄₆O₂S₂
Molecular Weight:466.793
Hs Code.:

Synonyms:2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

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Chemical Property of 2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

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Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

There total 14 articles about 2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 43161-11-1
5-iodo-2-methylpent-2-ene

: 85329-65-3
2-[(1R,6S)-6-(3-[1,3]Dithian-2-yl-propyl)-2,6-dimethyl-cyclohex-2-enylmethoxy]-tetrahydro-pyran

: 85354-58-1
2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

Guidance literature:: With n-butyllithium;
DOI:10.1246/cl.1982.1947

Reference yield:

: 85354-55-8
3-((1R,2R)-2-Hydroxymethyl-1,3-dimethyl-cyclohex-3-enyl)-propan-1-ol

: 85354-58-1
2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 5 steps

1: 60 mg / pyridine / 4 °C

2: sodium iodide / acetone / 2.2 h / Heating

3: 82 percent / p-toluenesulfonic acid / tetrahydrofuran

4: 73 percent / diethyl ether / 0 °C

5: 60 percent / 1.) n-BuLi / tetrahydrofuran / 1.) -30 deg C, 2 h, 2.) 0 deg C, 2 h

With pyridine; n-butyllithium; toluene-4-sulfonic acid; sodium iodide; In tetrahydrofuran; diethyl ether; acetone;
DOI:10.1246/bcsj.60.707

Reference yield:

: 85354-56-9
[(1R,6R)-6-(3-Iodo-propyl)-2,6-dimethyl-cyclohex-2-enyl]-methanol

: 85354-58-1
2-((1R,6S)-2,6-Dimethyl-6-{3-[2-(4-methyl-pent-3-enyl)-[1,3]dithian-2-yl]-propyl}-cyclohex-2-enylmethoxy)-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / p-toluenesulfonic acid / tetrahydrofuran

2: 73 percent / diethyl ether / 0 °C

3: 60 percent / 1.) n-BuLi / tetrahydrofuran / 1.) -30 deg C, 2 h, 2.) 0 deg C, 2 h

With n-butyllithium; toluene-4-sulfonic acid; In tetrahydrofuran; diethyl ether;
DOI:10.1246/bcsj.60.707