(2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC₆H₄tBu

Base Information

• Chemical Name: (2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC₆H₄tBu
• CAS No.: 1408316-23-3
• Molecular Formula: C₃₉H₅₈AuP
• Molecular Weight: 754.83
• Mol file: 1408316-23-3.mol

Synonyms:(2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC₆H₄tBu

Chemical Property of (2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC₆H₄tBu

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC₆H₄tBu

There total 1 articles about (2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC₆H₄tBu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

chloro[(2’,4’,6’-triisopropyl-[1,1’-biphenyl]-2-yl)di-tert-butylphosphine]gold(I) (1312108-97-6) + p-tert-butylphenylboronic acid (123324-71-0) → (2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC6H4tBu (1408316-23-3)

Guidance literature:

With caesium carbonate; In tetrahydrofuran; at 70 ℃; for 0.5h; Microwave irradiation;

DOI:10.1039/c2dt32129g

Reference yield: 88.0%

(2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)AuC6H4tBu (1408316-23-3) + 2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane 3,9-dioxide → [(2-di-tertbutylphosphino-2′,4′,6′-triisopropylbiphenyl)Au]2[PO3C5H8O3P]

Guidance literature:

In tetrahydrofuran; acetonitrile; at 25 ℃; for 16h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.8b01805

upstream raw materials:

chloro[(2’,4’,6’-triisopropyl-[1,1’-biphenyl]-2-yl)di-tert-butylphosphine]gold(I)

p-tert-butylphenylboronic acid