O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

Base Information

Chemical Name:O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate
CAS No.:177356-12-6
Molecular Formula:C₅₃H₄₆Cl₃NO₁₈
Molecular Weight:1091.3
Hs Code.:

O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

Synonyms:O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

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Chemical Property of O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

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Technology Process of O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

There total 1 articles about O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 545-06-2
trichloroacetonitrile

: O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-D-glucopyranose

: 177356-12-6
O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

Guidance literature:: With potassium carbonate; In dichloromethane; at 25 ℃; for 24h;
DOI:10.1002/prac.19963380148

Reference yield: 72.0%

: 87905-98-4
5-<(benzyloxycarbonyl)amino>pentanol

: 177356-12-6
O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

: 177356-13-7
5-<(benzyloxycarbonyl)amino>pentyl O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; at -10 ℃; for 0.333333h;
DOI:10.1002/prac.19963380148

Reference yield:

: 177356-12-6
O-<2,3-di-O-benzoyl-4,6-O-<(R)-1-methoxycarbonyl(ethylidene)>-β-D-galactopyranosyl>-(1->4)-2,3,6-tri-O-benzoyl-α-D-glucopyranosyl trichloroacetimidate

: (2R,4aR,6S,7R,8R,8aR)-6-[(2R,3S,4R,5R,6R)-6-(5-Benzyloxycarbonylamino-pentyloxy)-4,5-dihydroxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy]-7,8-dihydroxy-2-methyl-hexahydro-pyrano[3,2-d][1,3]dioxine-2-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 72 percent / BF₃*Et₂O / CH₂Cl₂ / 0.33 h / -10 °C

2: NaOMe / methanol / 24 h / Ambient temperature

3: 1 N aq. NaOH / methanol / 24 h / Ambient temperature

With sodium hydroxide; boron trifluoride diethyl etherate; sodium methylate; In methanol; dichloromethane;
DOI:10.1002/prac.19963380148