13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester

Base Information

• Chemical Name: 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester
• CAS No.: 113858-87-0
• Molecular Formula: C₃₂H₃₆N₄O₁₃
• Molecular Weight: 684.657

Synonyms:13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester

Chemical Property of 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester

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Technology Process of 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester

There total 4 articles about 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2,6-di(bromomethyl)benzoate (56263-51-5) → 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.111,15]triaconta-1(28),11,14,25(29),26-pentaene-29-carboxylic acid methyl ester (113858-87-0)

Guidance literature:

Multi-step reaction with 3 steps

1: NaH / tetrahydrofuran

2: Ce(NH₄)2(NO₃)6 / acetonitrile; H₂O

3: H₂SO₄ / ethanol; CH₂Cl₂

With ammonium cerium(IV) nitrate; sulfuric acid; sodium hydride; In tetrahydrofuran; ethanol; dichloromethane; water; acetonitrile;

DOI:10.1021/ja00217a047

Reference yield:

2,6-bis-(7-hydroxy-2,5-dioxaheptyl)-1,4-dimethoxybenzene (113858-79-0) → 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.111,15]triaconta-1(28),11,14,25(29),26-pentaene-29-carboxylic acid methyl ester (113858-87-0)

Guidance literature:

Multi-step reaction with 3 steps

1: NaH / tetrahydrofuran

2: Ce(NH₄)2(NO₃)6 / acetonitrile; H₂O

3: H₂SO₄ / ethanol; CH₂Cl₂

With ammonium cerium(IV) nitrate; sulfuric acid; sodium hydride; In tetrahydrofuran; ethanol; dichloromethane; water; acetonitrile;

DOI:10.1021/ja00217a047

Reference yield:

13,30-Dimethoxy-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.111,15]triaconta-1(29),11,13,15(30),25,27-hexaene-29-carboxylic acid methyl ester (113858-81-4) → 13-[(2,4-Dinitro-phenyl)-hydrazono]-30-oxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.111,15]triaconta-1(28),11,14,25(29),26-pentaene-29-carboxylic acid methyl ester (113858-87-0)

Guidance literature:

Multi-step reaction with 2 steps

1: Ce(NH₄)2(NO₃)6 / acetonitrile; H₂O

2: H₂SO₄ / ethanol; CH₂Cl₂

With ammonium cerium(IV) nitrate; sulfuric acid; In ethanol; dichloromethane; water; acetonitrile;

DOI:10.1021/ja00217a047

upstream raw materials:

13,30-Dioxo-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁸⁾,11,14,25⁽²⁹⁾,26-pentaene-29-carboxylic acid methyl ester

(2,4-dinitro-phenyl)-hydrazine

methyl 2,6-di(bromomethyl)benzoate

2,6-bis-(7-hydroxy-2,5-dioxaheptyl)-1,4-dimethoxybenzene

Downstream raw materials:

13-(2,4-Dinitro-phenylazo)-30-hydroxy-3,6,9,17,20,23-hexaoxa-tricyclo[23.3.1.1^11,15]triaconta-1⁽²⁹⁾,11,13,15⁽³⁰⁾,25,27-hexaene-29-carboxylic acid methyl ester

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