(2R,3R,4R)-anisomycin

Base Information

Chemical Name:(2R,3R,4R)-anisomycin
CAS No.:853092-28-1
Molecular Formula:C₁₄H₁₉NO₄
Molecular Weight:265.309
Hs Code.:

Synonyms:(2R,3R,4R)-anisomycin

Suppliers and Price of (2R,3R,4R)-anisomycin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2R,3R,4R)-anisomycin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2R,3R,4R)-anisomycin

There total 7 articles about (2R,3R,4R)-anisomycin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 853092-50-9
(2R,3R,4R)-N-(9-phenylfluoren-9-yl)anisomycin

: 853092-28-1
(2R,3R,4R)-anisomycin

Guidance literature:: With hydrogen; palladium on activated charcoal; In ethyl acetate; at 20 ℃; for 6h;
DOI:10.1021/jo050079w

Reference yield:

: 853092-38-3
(4R)-5-(p-methoxyphenyl)-4-(N-9-phenylfluoren-9-yl)aminopent-1-en-3-one

: 853092-28-1
(2R,3R,4R)-anisomycin

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / (S)-binaphtol-modified lithium aluminium hydride reagent / tetrahydrofuran / 1 h / -78 °C

2: 98 percent / Et₃N; 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h / 20 °C

3: 90 percent / iodine; NaHCO₃ / tetrahydrofuran; diethyl ether / 36 h / 20 °C

4: 84 percent / silver(I) trifluoroacetate / toluene / 6 h / Heating

5: 91 percent / hydrogen / Pd/C / ethyl acetate / 6 h / 20 °C

With dmap; (S)-binaphtol-modified lithium aluminium hydride reagent; hydrogen; iodine; silver trifluoroacetate; sodium hydrogencarbonate; triethylamine; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane; ethyl acetate; toluene;
DOI:10.1021/jo050079w

Reference yield:

: 359865-08-0
3-p-methoxyphenyl-2α-N-9-phenylfluoren-9-ylamino-1-propanal

: 853092-28-1
(2R,3R,4R)-anisomycin

Guidance literature:: Multi-step reaction with 7 steps

1: tetrahydrofuran / 0.5 h / -40 °C

2: 91 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 °C

3: 89 percent / (S)-binaphtol-modified lithium aluminium hydride reagent / tetrahydrofuran / 1 h / -78 °C

4: 98 percent / Et₃N; 4-(dimethylamino)pyridine / CH₂Cl₂ / 2 h / 20 °C

5: 90 percent / iodine; NaHCO₃ / tetrahydrofuran; diethyl ether / 36 h / 20 °C

6: 84 percent / silver(I) trifluoroacetate / toluene / 6 h / Heating

7: 91 percent / hydrogen / Pd/C / ethyl acetate / 6 h / 20 °C

With dmap; oxalyl dichloride; (S)-binaphtol-modified lithium aluminium hydride reagent; hydrogen; iodine; silver trifluoroacetate; sodium hydrogencarbonate; dimethyl sulfoxide; triethylamine; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane; ethyl acetate; toluene; 2: Swern oxidation;
DOI:10.1021/jo050079w