[1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate

Base Information

• Chemical Name: [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate
• CAS No.: 1276111-26-2
• Molecular Formula: CF₃O₃S*C₂₁H₂₀I
• Molecular Weight: 548.365
• Mol file: 1276111-26-2.mol

Synonyms:[1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate

Chemical Property of [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate

There total 2 articles about [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

trifluorormethanesulfonic acid (1493-13-6) + 4-iodo-biphenyl (1591-31-7) + 1,3,5-trimethyl-benzene (108-67-8) → [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate (1276111-26-2)

Guidance literature:

4-iodo-biphenyl; 1,3,5-trimethyl-benzene; With 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃;

DOI:10.1021/ja2008906

Reference yield:

4-iodo-biphenyl (1591-31-7) + 1,3,5-trimethyl-benzene (108-67-8) → [1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate (1276111-26-2)

Guidance literature:

With trifluorormethanesulfonic acid; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 2h;

DOI:10.1016/j.jfluchem.2015.09.015

Reference yield: 91.0%

[1,1′-biphenyl]-4-yl(mesityl)iodonium trifluoromethanesulfonate (1276111-26-2) + potassium ferrocyanide → 4-cyano-1,1'-biphenyl (2920-38-9)

Guidance literature:

With palladium diacetate; potassium carbonate; In N,N-dimethyl-formamide; at 130 ℃; for 2h;

DOI:10.1016/j.tetlet.2012.10.036

upstream raw materials:

trifluorormethanesulfonic acid

4-iodo-biphenyl

1,3,5-trimethyl-benzene

Downstream raw materials:

4-cyano-1,1'-biphenyl

4-bromo-1,1'-biphenyl

3-([1,1’-biphenyl]-4-yl)cyclohexan-1-one