2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

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Chemical Name:2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole
CAS No.:1443234-61-4
Molecular Formula:C₄₆H₄₄BrN₃S₄
Molecular Weight:847.043
Hs Code.:

Synonyms:2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

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Chemical Property of 2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

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Technology Process of 2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

There total 4 articles about 2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

: 1443234-60-3
2,6-bis(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

: 201802-67-7
4-(diphenylamino)phenyl boronic acid

: 1443234-61-4
2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In water; N,N-dimethyl-formamide; at 120 ℃; for 16h; Schlenk technique; Inert atmosphere;
DOI:10.1002/ejoc.201201629

Reference yield:

: 1010811-82-1
2,6-bis-(4-hexylthiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

: 1443234-61-4
2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

Guidance literature:: Multi-step reaction with 2 steps

1: N-Bromosuccinimide / chloroform; acetic acid / 4 h / 20 °C / Schlenk technique; Inert atmosphere; Darkness

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate / water; N,N-dimethyl-formamide / 16 h / 120 °C / Schlenk technique; Inert atmosphere

With N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In chloroform; water; acetic acid; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.201201629

Reference yield:

: 1693-86-3
3-hexylthiophene

: 1443234-61-4
2-(4-hexyl-5-(4-(diphenylamino)phen-1-yl)thiophen-2-yl)-6-(4-hexyl-5-bromothiophen-2-yl)benzo[1,2-d;4,5-d']bisthiazole

Guidance literature:: Multi-step reaction with 4 steps

1.1: 2,2,6,6-tetramethyl-piperidine; tert.-butyl lithium / tetrahydrofuran; pentane / -78 °C / Schlenk technique; Inert atmosphere

1.2: -78 - 20 °C / Schlenk technique; Inert atmosphere

2.1: N,N-dimethyl-formamide / 16 h / 120 °C / Schlenk technique; Inert atmosphere

3.1: N-Bromosuccinimide / chloroform; acetic acid / 4 h / 20 °C / Schlenk technique; Inert atmosphere; Darkness

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate / water; N,N-dimethyl-formamide / 16 h / 120 °C / Schlenk technique; Inert atmosphere

With 2,2,6,6-tetramethyl-piperidine; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tert.-butyl lithium; caesium carbonate; In tetrahydrofuran; chloroform; water; acetic acid; N,N-dimethyl-formamide; pentane;
DOI:10.1002/ejoc.201201629