(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

Base Information

Chemical Name:(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol
CAS No.:162472-61-9
Molecular Formula:C₁₆H₂₂O₃
Molecular Weight:262.349
Hs Code.:

Synonyms:(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

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Technology Process of (E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

There total 1 articles about (E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 162472-60-8
(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-enoic acid methyl ester

: 162472-61-9
(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran;
DOI:10.1248/cpb.42.2196

Reference yield:

: 162472-61-9
(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

: 1028275-49-1
C₃₀H₃₂O₆

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) D-DET, Ti(OPr)4, TBHP, 2.) NaAlH₂(OCH₂CH₂OMe)2, 3.) NaIO₄

2: pyridine, DMAP

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; dmap; sodium periodate; diethyl (2S,3S)-tartrate; sodium bis(2-methoxyethoxy)aluminium dihydride;
DOI:10.1248/cpb.42.2196

Reference yield:

: 162472-61-9
(E)-(S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pent-2-en-1-ol

: 162472-62-0
(3S,4S)-4-((4R,5R)-2,2-Dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-pentane-1,3-diol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium periodate; diethyl (2S,3S)-tartrate; sodium bis(2-methoxyethoxy)aluminium dihydride; Yield given. Multistep reaction;
DOI:10.1248/cpb.42.2196