C₅₀H₆₈O₁₀Si

Base Information

Chemical Name:C₅₀H₆₈O₁₀Si
CAS No.:1391927-56-2
Molecular Formula:C₅₀H₆₈O₁₀Si
Molecular Weight:857.169
Hs Code.:

C<sub>50</sub>H<sub>68</sub>O<sub>10</sub>Si

Synonyms:C₅₀H₆₈O₁₀Si

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Chemical Property of C₅₀H₆₈O₁₀Si

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Technology Process of C₅₀H₆₈O₁₀Si

There total 20 articles about C₅₀H₆₈O₁₀Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1391927-54-0
C₅₀H₆₆O₉Si

: 1391927-56-2
C₅₀H₆₈O₁₀Si

Guidance literature:: With pyridinium p-toluenesulfonate; gold(I) chloride; In methanol; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1021/ol301795a

Reference yield:

: 92512-41-9
C₂₁H₂₈O₃Si

: 1391927-56-2
C₅₀H₆₈O₁₀Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: sodium hydride / tetrahydrofuran / 0.33 h / 0 °C / Inert atmosphere

1.2: 2 h / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.75 h / -78 - -55 °C / Inert atmosphere

2.2: 0.5 h / -78 °C / Inert atmosphere

2.3: 0.33 h / -78 °C / Inert atmosphere

3.1: N,N,N',N'-tetramethyl-1,8-diaminonaphthalene / dichloromethane / 5 h / 20 °C / Inert atmosphere

4.1: pyridinium p-toluenesulfonate / methanol / 22 h / 40 °C / Inert atmosphere

5.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 0.5 h / 20 °C / Molecular sieve; Inert atmosphere

6.1: tetrahydrofuran / -78 °C / Inert atmosphere

6.2: 1 h / 20 °C / Molecular sieve; Inert atmosphere

7.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere

7.2: 0.83 h / -78 °C / Inert atmosphere

8.1: magnesium bromide diethyl etherate / dichloromethane / -78 - 0 °C / Inert atmosphere

9.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 20 h / 35 °C / Inert atmosphere

10.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 0 - 20 °C / pH 7 / aq. buffer; Inert atmosphere

11.1: pyridinium p-toluenesulfonate; gold(I) chloride / methanol / 4 h / 20 °C / Inert atmosphere

With n-butyllithium; tetrapropylammonium perruthennate; magnesium bromide diethyl etherate; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; potassium hexamethylsilazane; sodium hydride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; gold(I) chloride; In tetrahydrofuran; methanol; hexane; dichloromethane; toluene;
DOI:10.1021/ol301795a

Reference yield:

: (2S)-4-benzyloxy-2-(4-methoxybenzyloxy)-butyraldehyde

: 1391927-56-2
C₅₀H₆₈O₁₀Si

Guidance literature:: Multi-step reaction with 4 steps

1: magnesium bromide diethyl etherate / dichloromethane / -78 - 0 °C / Inert atmosphere

2: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 20 h / 35 °C / Inert atmosphere

3: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 1 h / 0 - 20 °C / pH 7 / aq. buffer; Inert atmosphere

4: pyridinium p-toluenesulfonate; gold(I) chloride / methanol / 4 h / 20 °C / Inert atmosphere

With magnesium bromide diethyl etherate; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; gold(I) chloride; In methanol; dichloromethane;
DOI:10.1021/ol301795a