methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate

Base Information

• Chemical Name: methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate
• CAS No.: 1448581-72-3
• Molecular Formula: C₉H₉N₃O₉S
• Molecular Weight: 335.251
• Mol file: 1448581-72-3.mol

Synonyms:methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate

Chemical Property of methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate

There total 1 articles about methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

methyl hydroxy(methyl)carbamate (6092-56-4) + 2,4-dinitrobenzenesulfonyl chloride (1656-44-6) → methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate (1448581-72-3)

Guidance literature:

With triethylamine; In dichloromethane; at 0 ℃; for 3h;

DOI:10.1002/chem.201601572

Reference yield: 99.0%

methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate (1448581-72-3) + 2-(2-chlorophenyl)-1-(1-(o-tolyl)-1H-imidazol-2-yl)ethan-1-one → C21H20ClN3O3

Guidance literature:

With 2,6-dimethylpyridine; C₃₈H₃₈N₄O₂Rh⁽¹⁺⁾*F₆P^(1-); In dimethyl sulfoxide; acetonitrile; at 20 ℃; for 2h; enantioselective reaction; Irradiation; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201601572

Reference yield: 99.0%

methyl (((2,4-dinitrophenyl)sulfonyl)oxy)(methyl)carbamate (1448581-72-3) + 2-(4-fluorophenyl)-1-(1-(o-tolyl)-1H-imidazol-2-yl)ethan-1-one → C21H20FN3O3

Guidance literature:

With 2,6-dimethylpyridine; C₃₈H₃₈N₄O₂Rh⁽¹⁺⁾*F₆P^(1-); In dimethyl sulfoxide; acetonitrile; at 20 ℃; for 1.5h; enantioselective reaction; Irradiation; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201601572

upstream raw materials:

methyl hydroxy(methyl)carbamate

2,4-dinitrobenzenesulfonyl chloride

Downstream raw materials:

(S)-methyl methyl(1-oxo-3-phenylpropan-2-yl)carbamate

(S)-methyl 5-(benzyloxy)-1-oxopentan-2-yl(methyl)carbamate

(S)-methyl 1-(4-methoxyphenyl)-3-oxopropan-2-yl(methyl)carbamate

(S)-methyl 1-cyclohexyl-3-oxopropan-2-yl(methyl)carbamate