methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate

Base Information

• Chemical Name: methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate
• CAS No.: 1287721-28-1
• Molecular Formula: C₁₃H₁₂Cl₃NO₄S
• Molecular Weight: 384.668

Synonyms:methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate

Chemical Property of methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate

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Technology Process of methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate

There total 1 articles about methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

methyl 3-bromo-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate (1287721-27-0) + thiophenol (108-98-5) → methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate (1287721-28-1)

Guidance literature:

With potassium carbonate; In acetonitrile; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1055/s-0030-1259074

Reference yield: 92.0%

ethyl 2-diazo-3-oxobutanoate (2009-97-4) + methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate (1287721-28-1) → ethyl 2-{[1-(methoxycarbonyl)-2-(phenylthio)vinyl][(2,2,2-trichloroethoxy)carbonyl]amino}-3-oxobutanoate (1287721-41-8)

Guidance literature:

With rhodium (II) octanoate dimer; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1055/s-0030-1259074

Reference yield: 88.0%

methyl 3-(phenylthio)-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate (1287721-28-1) + ethyl 2-diazo-3-(4-nitrophenyl)-3-oxopropanoate (75414-82-3) → methyl 2-{(2-ethoxy-1-(4-nitrobenzoyl)-2-oxoethyl)[(2,2,2-trichloroethoxy)carbonyl]amino}-3-(phenylthio)acrylate (1287721-35-0)

Guidance literature:

With rhodium (II) octanoate dimer; In dichloromethane; at 20 ℃; Inert atmosphere;

DOI:10.1055/s-0030-1259074

upstream raw materials:

methyl 3-bromo-2-{[(2,2,2-trichloroethoxy)carbonyl]amino}acrylate

thiophenol

Downstream raw materials:

methyl 2-{(1-(4-bromobenzoyl)-2-ethoxy-2-oxoethyl)[(2,2,2-trichloroethoxy)carbonyl]amino}-3-(phenylthio)acrylate

methyl 2-{(2-ethoxy-2-oxo-1-[4-(trifluoromethyl)benzoyl]ethyl)[(2,2,2-trichloroethoxy)carbonyl]amino}-3-(phenylthio)acrylate

methyl 2-{(2-ethoxy-1-(4-methoxybenzoyl)-2-oxoethyl)[(2,2,2-trichloroethoxy)carbonyl]amino}-3-(phenylthio)acrylate

methyl 2-{(2-ethoxy-1-(3-furoyl)-2-oxoethyl)[(2,2,2-trichloroethoxy)carbonyl]amino}-3-(phenylthio)acrylate

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