methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate

Base Information

• Chemical Name: methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate
• CAS No.: 1310552-56-7
• Molecular Formula: C₁₅H₁₃BrN₂O₄S
• Molecular Weight: 397.249
• Mol file: 1310552-56-7.mol

Synonyms:methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate

Chemical Property of methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate

There total 2 articles about methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-bromo-5-carbomethoxybenzenesulfonyl chloride (168969-13-9) + benzamidine monohydrochloride (1670-14-0) → C15H13BrN2O4S (1310552-56-7)

Guidance literature:

With potassium hydroxide; In dichloromethane; water; at 0 - 20 ℃;

DOI:10.1016/j.tet.2011.06.063

Reference yield: 92.0%

2-bromo-5-carbomethoxybenzenesulfonyl chloride (168969-13-9) + benzamidin (618-39-3) → methyl-3-(amino(phenyl)methylenesulfamoyl)-4-bromobenzoate (1310552-56-7)

Guidance literature:

With potassium hydroxide; In dichloromethane; at 0 - 20 ℃;

DOI:10.1080/00397911.2010.494815

Reference yield: 97.0%

C15H13BrN2O4S (1310552-56-7) → methyl-1,1-dioxo-3-phenyl-4H-1,2,4-benzothiadiazine-7-carboxylate (1210774-95-0)

Guidance literature:

With copper(l) iodide; N,N`-dimethylethylenediamine; In N,N-dimethyl-formamide; at 80 ℃; for 8h; Inert atmosphere;

DOI:10.1016/j.tet.2011.06.063

upstream raw materials:

2-bromo-5-carbomethoxybenzenesulfonyl chloride

benzamidin

benzamidine monohydrochloride

Downstream raw materials:

methyl-1,1-dioxo-3-phenyl-4H-1,2,4-benzothiadiazine-7-carboxylate