(4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

Base Information

Chemical Name:(4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane
CAS No.:214269-35-9
Molecular Formula:C₂₂H₂₆O₈
Molecular Weight:418.444
Hs Code.:

Synonyms:(4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

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Chemical Property of (4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

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Technology Process of (4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

There total 5 articles about (4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 123913-92-8
4-methoxy-2-(methoxymethoxy)phenol

: 214269-34-8
(4S,5S)-5-hydroxy-2,2-dimethyl-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

: 214269-35-9
(4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In toluene; benzene; for 24h; Heating;
DOI:10.1271/bbb.62.1550

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 214269-35-9
(4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) (n-Bu)2BOTf, Et₃N / 1.) CH₂Cl₂, -78 deg C, 2 h, 2.) CH₂Cl₂, -78 deg C, 1 h, then 0 deg C, 1 h

2: 99 percent / LiBH₄ / tetrahydrofuran; methanol / 24 h / Ambient temperature

3: 92 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 24 h / Ambient temperature

4: 96 percent / H₂ / Pd/C / ethyl acetate / Ambient temperature

5: 54 percent / PPh₃, diethyl azodicarboxylate / benzene; toluene / 24 h / Heating

With lithium borohydride; di-n-butylboryl trifluoromethanesulfonate; hydrogen; pyridinium p-toluenesulfonate; triethylamine; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; toluene; benzene;
DOI:10.1271/bbb.62.1550

Reference yield:

: 214269-31-5
(1S,2S)-2-benzyloxy-1-(3,4-methylenedioxyphenyl)-1,3-propanediol

: 214269-35-9
(4S,5R)-2,2-dimethyl-5-<<4-methoxy-2-(methoxymethoxy)phenyl>oxy>-4-(3,4-methylenedioxyphenyl)-1,3-dioxane

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 24 h / Ambient temperature

2: 96 percent / H₂ / Pd/C / ethyl acetate / Ambient temperature

3: 54 percent / PPh₃, diethyl azodicarboxylate / benzene; toluene / 24 h / Heating

With hydrogen; pyridinium p-toluenesulfonate; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In dichloromethane; ethyl acetate; toluene; benzene;
DOI:10.1271/bbb.62.1550