[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

Base Information

Chemical Name:[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol
CAS No.:183279-62-1
Molecular Formula:C₄₁H₈₄O₄Si₃
Molecular Weight:725.372
Hs Code.:

[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

Synonyms:[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

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Chemical Property of [(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

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Technology Process of [(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

There total 1 articles about [(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: (1R,4S)-2-[1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enecarbonyl]-4,7,7-trimethyl-2-aza-bicyclo[2.2.1]heptan-3-one

: 183279-62-1
[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

Guidance literature:: With lithium borohydride; In tetrahydrofuran; for 48h; Ambient temperature;
DOI:10.1021/jo961613q

Reference yield:

: 183279-62-1
[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

: 108543-38-0
(-)-cassioside

Guidance literature:: Multi-step reaction with 5 steps

1: 2,6-di-tert-butyl-4-methylpyridine, molecular sieves 4 Angstroems

2: CH₂Cl₂ / -90 °C

3: Pd(OAc)2, AgOTf, I₂ / acetonitrile; CH₂Cl₂ / Ambient temperature

4: NaI, Et₃N / acetone / Ambient temperature

5: 80 percent / CAN / acetonitrile; H₂O

With palladium diacetate; 2,6-di-tert-butyl-4-methylpyridine; ammonium cerium(IV) nitrate; 4 A molecular sieve; iodine; silver trifluoromethanesulfonate; triethylamine; sodium iodide; In dichloromethane; water; acetone; acetonitrile;
DOI:10.1021/jo961613q

Reference yield:

: 183279-62-1
[(1S,2S)-1,3-Dimethyl-4-triisopropylsilanyloxy-2-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-cyclohex-3-enyl]-methanol

: (3S,4S)-2-Iodo-2,4-dimethyl-3-((E)-4-triisopropylsilanyloxy-3-triisopropylsilanyloxymethyl-but-1-enyl)-4-[(2R,3R,4S,5R,6R)-3,4,5-tris-(4-methoxy-benzyloxy)-6-(4-methoxy-benzyloxymethyl)-tetrahydro-pyran-2-yloxymethyl]-cyclohexanone

Guidance literature:: Multi-step reaction with 3 steps

1: 2,6-di-tert-butyl-4-methylpyridine, molecular sieves 4 Angstroems

2: CH₂Cl₂ / -90 °C

3: Pd(OAc)2, AgOTf, I₂ / acetonitrile; CH₂Cl₂ / Ambient temperature

With palladium diacetate; 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; iodine; silver trifluoromethanesulfonate; In dichloromethane; acetonitrile;
DOI:10.1021/jo961613q