trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

Base Information

Chemical Name:trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane
CAS No.:99598-58-0
Molecular Formula:C₂₇H₃₀O₄S₃
Molecular Weight:514.731
Hs Code.:

Synonyms:trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

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Chemical Property of trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

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Technology Process of trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

There total 4 articles about trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 4β-<2-(4-methoxybenzocyclobutenyl)-1,1-trimethylenedithio>ethyl-5α-methoxymethyl-3-phenylthiomethylenefuran-2-one

: 99598-58-0
trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

Guidance literature:: In 1,2-dichloro-benzene; at 180 ℃; for 14h;
DOI:10.1016/S0040-4020(01)96631-1

Reference yield:

: 108-98-5
thiophenol

: 99598-58-0
trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) methanesulfonyl chloride; 2.) 10percent hydrochloric acid / 1.) 4-dimethylaminopyridine / 1.) pyridine, r.t., 23 h; 2.) r.t., 4 h

2: 76 percent / 1,2-dichloro-benzene / 14 h / 180 °C

With hydrogenchloride; methanesulfonyl chloride; dmap; In 1,2-dichloro-benzene;
DOI:10.1016/S0040-4020(01)96631-1

Reference yield:

: 96955-85-0
(4S,5S)-4-[2-(3-Methoxy-bicyclo[4.2.0]octa-1,3,5-trien-7-ylmethyl)-[1,3]dithian-2-yl]-5-methoxymethyl-dihydro-furan-2-one

: 99598-58-0
trans-4,5-(4-methoxybenzo)-1β,7aβ-(2α-methoxymethyl-5-oxofuro)-7-phenylthio-2,2-trimethylenedithiohydrindane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) 60percent sodium hydride; 2.) 10percent hydrochloric acid / 1.) benzene, r.t., 30 min; 2.) r.t., 2 h, water

2: 1.) methanesulfonyl chloride; 2.) 10percent hydrochloric acid / 1.) 4-dimethylaminopyridine / 1.) pyridine, r.t., 23 h; 2.) r.t., 4 h

3: 76 percent / 1,2-dichloro-benzene / 14 h / 180 °C

With hydrogenchloride; sodium hydride; methanesulfonyl chloride; dmap; In 1,2-dichloro-benzene;
DOI:10.1016/S0040-4020(01)96631-1