p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside

Base Information

• Chemical Name: p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside
• CAS No.: 1332839-07-2
• Molecular Formula: C₃₂H₃₅NO₁₅
• Molecular Weight: 673.628
• Mol file: 1332839-07-2.mol

Synonyms:p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside

Chemical Property of p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside

There total 3 articles about p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-3,4-O-isopropylidene-α-L-arabinopyranoside (1332839-05-0) → p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside (1332839-07-2)

Guidance literature:

With acetic acid; In water; at 80 ℃; for 3h;

DOI:10.1016/j.tetasy.2011.06.025

Reference yield:

p-methoxyphenyl 3,4-O-isopropylidene-α-L-arabinopyranoside (959793-40-9) → p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside (1332839-07-2)

Guidance literature:

Multi-step reaction with 2 steps

1: N-iodo-succinimide; lanthanum(lll) triflate / dichloromethane / 0.75 h / 5 - 10 °C / Molecular sieve; Inert atmosphere

2: acetic acid / water / 3 h / 80 °C

With N-iodo-succinimide; acetic acid; lanthanum(lll) triflate; In dichloromethane; water;

DOI:10.1016/j.tetasy.2011.06.025

Reference yield:

p-methylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside (172847-90-4) → p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-α-L-arabinopyranoside (1332839-07-2)

Guidance literature:

Multi-step reaction with 2 steps

1: N-iodo-succinimide; lanthanum(lll) triflate / dichloromethane / 0.75 h / 5 - 10 °C / Molecular sieve; Inert atmosphere

2: acetic acid / water / 3 h / 80 °C

With N-iodo-succinimide; acetic acid; lanthanum(lll) triflate; In dichloromethane; water;

DOI:10.1016/j.tetasy.2011.06.025

upstream raw materials:

p-methoxyphenyl 3,4-O-isopropylidene-α-L-arabinopyranoside

p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-3,4-O-isopropylidene-α-L-arabinopyranoside

p-methylphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

Downstream raw materials:

p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-4-O-acetyl-α-L-arabinopyranoside

p-methoxyphenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->2)-4-O-acetyl-3-O-(2,3,4-tri-O-acetyl-α-L-arabinopyranosyl)-α-L-arabinopyranoside

p-methoxyphenyl 3,4,6-tri-O-acetyl-2-acetamido-2-deoxy-β-D-glucopyranosyl-(1->2)-4-O-acetyl-3-O-(2,3,4-tri-O-acetyl-α-L-arabinopyranosyl)-α-L-arabinopyranoside

p-methoxyphenyl 2-acetamido-2-deoxy-β-D-glucopyranosyl-(1->2)-3-O-(α-L-arabinopyranosyl)-α-L-arabinopyranoside