α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

Base Information

Chemical Name:α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose
CAS No.:96689-96-2
Molecular Formula:C₂₂H₂₈O₁₁
Molecular Weight:468.458
Hs Code.:

Synonyms:α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

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Chemical Property of α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

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Technology Process of α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

There total 13 articles about α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 108-24-7
acetic anhydride

: (3R,4R,5S,6R)-2-(2,4-Dimethoxy-phenyl)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

: 96689-96-2
α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

Guidance literature:: With pyridine; dmap; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1021/ja00300a036

Reference yield:

: 4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9
2,3,4,6-Tetra-O-benzyl-D-glucopyranose

: 96689-96-2
α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

Guidance literature:: Multi-step reaction with 4 steps

1: 69 percent / tri-n-butylphosphine / CH₂Cl₂ / 0.5 h / 0 °C

2: siver(I) triflate / diethyl ether / 2 h / Ambient temperature

3: 85 percent / H₂ / 10percent Pd/C / tetrahydrofuran / 12 h / 25 °C

4: 66 percent / pyridine, DMAP / CH₂Cl₂ / 1 h / Ambient temperature

With pyridine; dmap; tributylphosphine; hydrogen; silver trifluoromethanesulfonate; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ja00300a036

Reference yield:

: 74352-41-3
2-Pyridyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside

: 96689-96-2
α-1-deoxy-1-(C-2',4'-dimethoxyphenyl)-2,3,4,6-tetra-O-acetyl-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: siver(I) triflate / diethyl ether / 2 h / Ambient temperature

2: 85 percent / H₂ / 10percent Pd/C / tetrahydrofuran / 12 h / 25 °C

3: 66 percent / pyridine, DMAP / CH₂Cl₂ / 1 h / Ambient temperature

With pyridine; dmap; hydrogen; silver trifluoromethanesulfonate; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ja00300a036