1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

Base Information

Chemical Name:1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol
CAS No.:577978-85-9
Molecular Formula:C₃₄H₃₅NO₄
Molecular Weight:521.656
Hs Code.:

Synonyms:1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

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Chemical Property of 1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

Chemical Property:

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Technology Process of 1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

There total 10 articles about 1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 577978-84-8
1,2-dideoxy-3,4,5,6-di-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

: 577978-85-9
1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

Guidance literature:: With Dowex 50W-X₈ resin; In methanol; at 20 ℃; for 24h;

Reference yield:

: phenylmagnesium bromide

: 577978-85-9
1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / CuI / tetrahydrofuran / 1 h / -40 °C

2: 98 percent / pyridine / CH₂Cl₂ / 0.17 h / -10 °C

3: NaN₃ / dimethylformamide / 3 h / 20 °C

4: H₂ / 10 percent Pd/C / ethyl acetate / 20 °C

5: 0.99 g / Et₃N; Pb(NO₃)2 / CH₂Cl₂ / 24 h / 20 °C

6: 95 percent / Dowex 50W-X₈ resin / aq. methanol / 24 h / 20 °C

With pyridine; copper(l) iodide; sodium azide; lead(II) nitrate; Dowex 50W-X₈ resin; hydrogen; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 1: Grignard reaction;

Reference yield:

: 6322-07-2
D-gulono-1,4-lactone

: 577978-85-9
1,2-dideoxy-3,4-O-isopropylidene-1-phenyl-2-[(9-phenyl-9-fluorenyl)-amino]-D-iditol

Guidance literature:: Multi-step reaction with 9 steps

1.1: TsOH / acetone; methanol / 2 h / 20 °C

1.2: 95 percent / NaBH₄ / ethanol / 3 h / Heating

2.1: 86 percent / Et₃N / CH₂Cl₂ / 0.08 h / -40 °C

3.1: 93 percent / K₂CO₃ / methanol / 2 h / 20 °C

4.1: 97 percent / CuI / tetrahydrofuran / 1 h / -40 °C

5.1: 98 percent / pyridine / CH₂Cl₂ / 0.17 h / -10 °C

6.1: NaN₃ / dimethylformamide / 3 h / 20 °C

7.1: H₂ / 10 percent Pd/C / ethyl acetate / 20 °C

8.1: 0.99 g / Et₃N; Pb(NO₃)2 / CH₂Cl₂ / 24 h / 20 °C

9.1: 95 percent / Dowex 50W-X₈ resin / aq. methanol / 24 h / 20 °C

With pyridine; copper(l) iodide; sodium azide; lead(II) nitrate; Dowex 50W-X₈ resin; hydrogen; potassium carbonate; toluene-4-sulfonic acid; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; acetone; 4.1: Grignard reaction;