[Ir(1,2-diphenylbenzimidazole)₂(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF₆]

Base Information

• Chemical Name: [Ir(1,2-diphenylbenzimidazole)₂(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF₆]
• CAS No.: 1609033-42-2
• Molecular Formula: C₅₀H₃₄IrN₆O₄*F₆P
• Molecular Weight: 1120.04
• Mol file: 1609033-42-2.mol

Synonyms:[Ir(1,2-diphenylbenzimidazole)₂(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF₆]

Chemical Property of [Ir(1,2-diphenylbenzimidazole)₂(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Ir(1,2-diphenylbenzimidazole)₂(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF₆]

There total 2 articles about [Ir(1,2-diphenylbenzimidazole)₂(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

ammonium hexafluorophosphate + [Ir(1,2-diphenyl-1H-benzoimidazole)2(μ-Cl)]2 + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) → [Ir(1,2-diphenylbenzimidazole)2(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF6] (1609033-42-2)

Guidance literature:

[Ir(1,2-diphenyl-1H-benzoimidazole)₂(μ-Cl)]₂; 2,2'-Bipyridine-4,4'-dicarboxylic acid; In methanol; dichloromethane; at 65 ℃; Inert atmosphere;

ammonium hexafluorophosphate; for 0.5h; Inert atmosphere;

DOI:10.1002/ejic.201501068

Reference yield: 53.0%

ammonium hexafluorophosphate + [Ir(1,2-diphenyl-1H-benzoimidazole)2(μ-Cl)]2 + 2,2'-Bipyridine-4,4'-dicarboxylic acid (6813-38-3) → [Ir(1,2-diphenylbenzimidazole)2(2,2'-bipyridine-4,4'-dicarboxylic acid)][PF6] (1609033-42-2)

Guidance literature:

[Ir(1,2-diphenyl-1H-benzoimidazole)₂(μ-Cl)]₂; 2,2'-Bipyridine-4,4'-dicarboxylic acid; In methanol; dichloromethane; for 7h; Inert atmosphere; Darkness; Reflux;

ammonium hexafluorophosphate; In methanol; dichloromethane; for 0.5h; Inert atmosphere;

DOI:10.1016/j.ica.2014.02.024

upstream raw materials:

2,2'-Bipyridine-4,4'-dicarboxylic acid