phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

Base Information

Chemical Name:phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose
CAS No.:195865-18-0
Molecular Formula:C₂₃H₂₄N₂O₇S
Molecular Weight:472.519
Hs Code.:

Synonyms:phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

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Chemical Property of phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

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Technology Process of phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

There total 2 articles about phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 4551-15-9
phenylthiotrimethylsilane

: 196512-07-9
3-N-allyloxycarbonyl-1,4-di-O-p-nitrobenzoyl-3-amino-2,3,6-trideoxy-α-L-lyxo-hexopyranose

: 195865-18-0
phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/S0968-0896(01)00411-4

Reference yield:

: 3-N-allyloxycarbonyldaunosamine

: 195865-18-0
phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 2.2 g / pyridine / 1 h / 20 °C

2: 95 percent / CF₃SO₃SiMe₃ / CH₂Cl₂ / 2 h / 20 °C

With pyridine; trimethylsilyl trifluoromethanesulfonate; In dichloromethane;
DOI:10.1016/S0968-0896(01)00411-4

Reference yield: 84.0%

: 452071-62-4
p-methoxybenzyl 2,3,6-trideoxy-α-L-lyxo-hexopyranoside

: 195865-18-0
phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose

: 452071-63-5
p-methoxybenzyl 4-O-(3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-2,3,6-trideoxy-α-L-lyxo-hexopyranosyl)-2,3,6-trideoxy-α-L-lyxo-hexopyranoside

Guidance literature:: p-methoxybenzyl 2,3,6-trideoxy-α-L-lyxo-hexopyranoside; phenyl 3-N-allyloxycarbonyl-4-O-p-nitrobenzoyl-3-amino-1-thio-2,3,6-trideoxy-α-L-lyxo-hexopyranose; With iodonium di(2,4,6-trimethylpyridine) perchlorate; 4 A molecular sieve; In diethyl ether; 1,2-dichloro-ethane; at 10 ℃; for 1h;

With triphenylphosphine; In diethyl ether; 1,2-dichloro-ethane; for 1h;
DOI:10.1016/S0968-0896(01)00411-4