ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

Base Information

Chemical Name:ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate
CAS No.:123887-04-7
Molecular Formula:C₂₅H₃₆O₆
Molecular Weight:432.557
Hs Code.:

Synonyms:ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

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Chemical Property of ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

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Technology Process of ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

There total 12 articles about ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 123886-97-5
3-[(1S,3R,4S,5R)-3-(2-Acetoxy-ethyl)-5-hydroxy-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

: 65-85-0,8013-63-6
benzoic acid

: 123887-03-6
ethyl 3-<5α-(2-acetoxyethyl)-4,6,6-trimethyl-3-cyclohexen-1α-yl>propionate

: 123887-04-7
ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; for 15h; Ambient temperature;
DOI:10.1248/cpb.36.4722

Reference yield:

: 123886-96-4
3-[(1S,3R,4S,5R)-5-Benzyloxycarbonyloxy-2,2,4-trimethyl-3-(3-oxo-butyl)-cyclohexyl]-propionic acid ethyl ester

: 123887-04-7
ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

Guidance literature:: Multi-step reaction with 3 steps

1: 82.6 percent / mCPBA / 1,2-dichloro-ethane / 44 h / 55 °C

2: 89.5 percent / hydrogen / 10percent Pd-C / ethanol / 0.5 h / Ambient temperature

3: 88 percent / diethyl azodicarboxylate, triphenylphosphine / tetrahydrofuran / 15 h / Ambient temperature

With hydrogen; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; ethanol; 1,2-dichloro-ethane;
DOI:10.1248/cpb.36.4722

Reference yield:

: 123887-01-4
3-[(1S,3R,4S,5R)-3-(2-Acetoxy-ethyl)-5-benzyloxycarbonyloxy-2,2,4-trimethyl-cyclohexyl]-propionic acid ethyl ester

: 123887-04-7
ethyl 3-<5α-(2-acetoxyethyl)-3β-benzoyloxy-4,6,6-trimethylcyclohexan-1α-yl>propionate

Guidance literature:: Multi-step reaction with 2 steps

1: 89.5 percent / hydrogen / 10percent Pd-C / ethanol / 0.5 h / Ambient temperature

2: 88 percent / diethyl azodicarboxylate, triphenylphosphine / tetrahydrofuran / 15 h / Ambient temperature

With hydrogen; triphenylphosphine; diethylazodicarboxylate; palladium on activated charcoal; In tetrahydrofuran; ethanol;
DOI:10.1248/cpb.36.4722