tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum⁽⁰⁾

Base Information

• Chemical Name: tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum⁽⁰⁾
• CAS No.: 16632-93-2
• Molecular Formula: C₂₈H₁₆MoN₂O₄
• Molecular Weight: 540.386
• Mol file: 16632-93-2.mol

Synonyms:tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum⁽⁰⁾

Chemical Property of tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum⁽⁰⁾

Chemical Property:

Purity/Quality:

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• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum⁽⁰⁾

There total 2 articles about tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

bathophenanthroline (1662-01-7) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum(0) (16632-93-2)

Guidance literature:

In toluene; at 80 ℃; for 4h; Schlenk technique; Inert atmosphere;

DOI:10.1002/ejic.201600647

Reference yield:

[Mo(CO)5(C24H16N2)] (176260-44-9) → tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum(0) (16632-93-2)

Guidance literature:

In toluene; byproducts: CO; 25.0°C, 0.1-100 MPa; Kinetics;

Reference yield: 63.0%

tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N')molybdenum(0) (16632-93-2) + Dibutyl maleate (105-76-0,29014-71-9) → [molybdenum(CO)2(4,7-diphenyl-1,10-phenanthroline)(dibutylfumarate)2] (390387-45-8)

Guidance literature:

In toluene; all manipulations under N2 atm.; org. compd. added to soln. of complex, refluxed for 21 h; concd., chromy., solvent removed, dried in vac., elem. anal.;

DOI:10.1002/1521-3749(200111)627:11<2481::AID-ZAAC2481>3.0.CO;2-B

upstream raw materials:

bathophenanthroline

molybdenum hexacarbonyl

[Mo(CO)5(C₂₄H₁₆N₂)]

Downstream raw materials:

[molybdenum(CO)2(4,7-diphenyl-1,10-phenanthroline)(dibutylfumarate)2]