(Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

Base Information

Chemical Name:(Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one
CAS No.:164713-03-5
Molecular Formula:C₃₆H₅₀O₄Si
Molecular Weight:574.876
Hs Code.:

Synonyms:(Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

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Technology Process of (Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

There total 13 articles about (Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 164524-11-2
(1R,2R,2'S,Z)-2-(9'-oxo-2',3',6',7',8',9'-hexahydrooxonin-2'-yl)cyclopropanecarbaldehyde

: 164524-06-5
tert-Butyl-[(R)-1-((E)-2-iodo-vinyl)-hexyloxy]-diphenyl-silane

: (Z)-(S)-9-{(1R,2R)-2-[(E)-(1S,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

: 164713-03-5
(Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

: (2S,3R)-3-(methoxymethoxy)-2-methylpent-4-enoic acid

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; Product distribution; multistep reaction;
DOI:10.1021/jo962312j

Reference yield: 55.0%

: 1201126-87-5
C₃₆H₄₈O₄Si

: (Z)-(S)-9-{(1R,2R)-2-[(E)-(1S,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

: 164713-03-5
(Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

Guidance literature:: With chromium dichloride; water; sodium acetate; sodium sulfate; In N,N-dimethyl-formamide; at 20 - 50 ℃; for 24h; Inert atmosphere;
DOI:10.1002/chem.200901685

Reference yield: 44.0%

: 164524-11-2
(1R,2R,2'S,Z)-2-(9'-oxo-2',3',6',7',8',9'-hexahydrooxonin-2'-yl)cyclopropanecarbaldehyde

: 164524-06-5
tert-Butyl-[(R)-1-((E)-2-iodo-vinyl)-hexyloxy]-diphenyl-silane

: (Z)-(S)-9-{(1R,2R)-2-[(E)-(1S,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

: 164713-03-5
(Z)-(S)-9-{(1R,2R)-2-[(E)-(1R,4R)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-non-2-enyl]-cyclopropyl}-4,5,8,9-tetrahydro-3H-oxonin-2-one

Guidance literature:: With chromium chloride; nickel dichloride; In dimethyl sulfoxide; for 3h; Yields of byproduct given; Ambient temperature;
DOI:10.1021/jo962312j