14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

Base Information

Chemical Name:14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene
CAS No.:101933-66-8
Molecular Formula:C₂₇H₄₀O₅Si
Molecular Weight:472.697
Hs Code.:

Synonyms:14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

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Chemical Property of 14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

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Technology Process of 14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

There total 6 articles about 14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 101933-68-0
Benzoic acid (1S,2R,7R,9S,10R,11R)-11-(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-2,5-dimethyl-8-oxa-tricyclo[7.2.1.0^2,7]dodec-5-en-1-ylmethyl ester

: 101933-66-8
14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; for 2h; Ambient temperature;
DOI:10.1021/jo00361a001

Reference yield:

: 101933-65-7
3α,4α-dihydroxy-1β-((benzoyloxy)methyl)-1-(1-methyl-4-hydroxy-4-methylcyclohex-2-enyl)-2β-((tert-butyldimethylsilyl)oxy)cyclopentane

: 101933-66-8
14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

: 101933-68-0
Benzoic acid (1S,2R,7R,9S,10R,11R)-11-(tert-butyl-dimethyl-silanyloxy)-10-hydroxy-2,5-dimethyl-8-oxa-tricyclo[7.2.1.0^2,7]dodec-5-en-1-ylmethyl ester

Guidance literature:: With toluene-4-sulfonic acid; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/jo00361a001

Reference yield:

: 101933-52-2
3α,4α-diacetoxy-1β-((benzoyloxy)methyl)-1-(1-methyl-4-oxocyclohex-2-enyl)-2β-((tert-butyldimethylsilyl)oxy)cyclopentane

: 101933-66-8
14-(benzyloxy)-12β-((tert-butyldimethylsilyl)oxy)-3α-hydroxy-13-nortrichothec-9-ene

Guidance literature:: Multi-step reaction with 3 steps

1: 919 mg / diethyl ether; tetrahydrofuran / 2.5 h / -78 °C

2: 728 mg / potassium carbonate / methanol; H₂O / 2 h / Ambient temperature

3: p-toluenesulfonic acid / CH₂Cl₂ / 2 h / Ambient temperature

With potassium carbonate; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water;
DOI:10.1021/jo00361a001