8-Quinolineboronic acid

Base Information

Chemical Name:8-Quinolineboronic acid
CAS No.:86-58-8
Molecular Formula:C9H8BNO2
Molecular Weight:172.979
Hs Code.:29339900
European Community (EC) Number:626-756-7
UNII:5QS1A25IJ6
DSSTox Substance ID:DTXSID00370270
Nikkaji Number:J2.010.463E
Wikidata:Q27262755
Mol file:86-58-8.mol

Synonyms:8-quinolineboronic acid

Suppliers and Price of 8-Quinolineboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

AHH
Quinoline-8-boronicacid 98%
250g
$ 7818.00

AK Scientific
8-Quinolineboronicacid
10g
$ 60.00

Alfa Aesar
Quinoline-8-boronic acid, 99%
250mg
$ 84.20

Alfa Aesar
Quinoline-8-boronic acid, 99%
1g
$ 228.00

Alichem
Quinoline-8-boronicacid
25g
$ 178.26

ChemBridge Corporation
quinolin-8-ylboronicacid 95%
1 g
$ 46.00

Chemcia Scientific
Quinoline-8-boronicacid 97%
100 G
$ 495.00

Chemenu
quinolin-8-yl-8-boronicacid 0.95
10g
$ 100.00

Chem-Impex
Quinoline-8-boronicacid,95-105%(Assaybytitration) 95-105%(Assaybytitration)
1G
$ 199.18

Chem-Impex
Quinoline-8-boronicacid,95-105%(Assaybytitration) 95-105%(Assaybytitration)
200MG
$ 50.40

Total 157 raw suppliers

Chemical Property of 8-Quinolineboronic acid

Chemical Property:

Appearance/Colour:yellow crystal powder
Melting Point:350 °C
Boiling Point:400.261 °C at 760 mmHg
PKA:4.61±0.30(Predicted)
Flash Point:195.871 °C
PSA：53.35000
Density:1.289 g/cm³
LogP:-0.08540
Storage Temp.:0-6°C
Solubility.:soluble in Methanol
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:173.0648087
Heavy Atom Count:13
Complexity:177

Purity/Quality:

99% ^*data from raw suppliers

Quinoline-8-boronicacid 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38-36/38
Safety Statements: 26-37/39-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:B(C1=C2C(=CC=C1)C=CC=N2)(O)O
Uses suzuki reaction Reactant involved in:C-H and C-S bond activationsSynthesis of pyridazine via sequential amination / Suzuki coupling / alkylation reactionsSuzuki-Miyaura coupling reactions for synthesis of biaryl monophosphorus ligands, fused tricyclic oxa-quinolones, or substituted β-amino acidsCopper-catalyzed azidation with sodium azideStudies of the affect of fluoride on the stability of boronic acids during click reactions

Technology Process of 8-Quinolineboronic acid

There total 9 articles about 8-Quinolineboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 16567-18-3
8-bromoquinoline

: 121-43-7,63156-11-6
Trimethyl borate

: 7732-18-5
water

: 86-58-8
8-quinolinylboronic acid

Guidance literature:: 8-bromoquinoline; With n-butyllithium; In tetrahydrofuran; at -78 - 20 ℃; for 16h;

Trimethyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 16h;

water; In tetrahydrofuran; at 0 ℃;

Reference yield: 64.0%

: 16567-18-3
8-bromoquinoline

: 5419-55-6
Triisopropyl borate

: 86-58-8
8-quinolinylboronic acid

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; toluene; at -60 ℃; Flow reactor;
DOI:10.1002/chem.201303736

Reference yield: 60.0%

: 16567-18-3
8-bromoquinoline

: 86-58-8
8-quinolinylboronic acid

Guidance literature:: 8-bromoquinoline; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h;

With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;

With hydrogenchloride; In tetrahydrofuran; hexane;
DOI:10.1021/jo026850+