η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

Base Information

Chemical Name:η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate
CAS No.:852414-82-5
Molecular Formula:C₁₉H₁₈ClFeO*F₆P
Molecular Weight:498.615
Hs Code.:

Synonyms:η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

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Chemical Property of η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

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Technology Process of η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

There total 1 articles about η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 576-26-1,25134-01-4
2.6-dimethylphenol

: η-cyclopentadienyl-η-1,4-dichlorobenzeneiron(II) hexafluorophosphate

: 852414-82-5
η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

Guidance literature:: With sodium hydride; In tetrahydrofuran; mineral oil; (N2); phenol was stirred with NaH/mineral oil in THF for 15-20 min; soln. was added dropwise to stirred suspn. of Fe complex in THF at -78°C; mixt. was warmed to -20°C and stirred; few drops of H2O added; passed through Celite, which subsequently washedwith CH2Cl2; solvent removed (vac.); redissolved in CH2Cl2; washed (NH4 PF6, NaOH, H2O); org. layer dried (MgSO4); solvent removed (vac.); residue triturated with ether; elem. anal.;
DOI:10.1016/j.jorganchem.2005.01.032

Reference yield: 94.0%

: 852414-82-5
η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

: 107-15-3,85404-18-8
ethylenediamine

: 852415-14-6
η6-[1-(2,6-dimethylphenoxy)-4-(N-(2-aminoethyl)-amino)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

Guidance literature:: With potassium carbonate; In tetrahydrofuran; (N2); Fe complex and ethylenediamine (2 equiv.) were stirred with K2CO3 in THF at room temp. for 5 h; filtered; washed (CH2Cl2); solvent removed (vac.); residue triturated with ether;
DOI:10.1016/j.jorganchem.2005.01.032

Reference yield: 77.0%

: 852414-82-5
η6-[1-chloro-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

: 24966-39-0
2,6-dichlorothiophenol

: 852415-10-2
η6-[1-(2,6-dichlorophenylthio)-4-(2,6-dimethylphenoxy)benzene]-η5-cyclopentadienyliron(II) hexafluorophosphate

Guidance literature:: With sodium hydride; In tetrahydrofuran; mineral oil; (N2); thiol was stirred with NaH/mineral oil in THF for 15-20 min; obtained soln. was added via syringe to soln. of Fe complex in THF; mixt. wasstirred for 3 h; few drops of H2O added; filtered through Celite, which washed with CH2Cl2; solvent removed (vac.); redissolved in CH2Cl2; washed (satd. aq. NH4PF6, NaOH, H2O); org.layer dried (MgSO4); solvent removed (vac.); triturated (ether); elem. anal.;
DOI:10.1016/j.jorganchem.2005.01.032