C₂₅H₃₂O₆

Base Information

• Chemical Name: C₂₅H₃₂O₆
• CAS No.: 1417721-80-2
• Molecular Formula: C₂₅H₃₂O₆
• Molecular Weight: 428.525
• Mol file: 1417721-80-2.mol

Synonyms:C₂₅H₃₂O₆

Chemical Property of C₂₅H₃₂O₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₅H₃₂O₆

There total 6 articles about C₂₅H₃₂O₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(3R,5S,6R)-3,5-bis(benzyloxy)-2-((R)-hex-5-en-2-yloxy)-6-methyltetrahydro-2H-pyran α-anomer (1417721-81-3) → C25H32O6 (1417721-80-2)

Guidance literature:

With sodium periodate; ruthenium(III) trichloride hydrate; In dichloromethane; water; acetonitrile; for 2.75h;

DOI:10.1002/anie.201206797

Reference yield:

(2S,3R,5S,6R)-3,5-bis(benzyloxy)-2-methoxy-6-methyltetrahydro-2H-pyran (85451-36-1) → C25H32O6 (1417721-80-2)

Guidance literature:

Multi-step reaction with 4 steps

1: acetic acid; sulfuric acid / 2 h / 100 °C

2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.5 h

3: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 3 h / -20 - 0 °C

4: sodium periodate; ruthenium(III) trichloride hydrate / water; dichloromethane; acetonitrile / 2.75 h

With sodium periodate; trimethylsilyl trifluoromethanesulfonate; ruthenium(III) trichloride hydrate; sulfuric acid; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; water; acetonitrile;

DOI:10.1002/anie.201206797

Reference yield:

C20H24O4 → C25H32O6 (1417721-80-2)

Guidance literature:

Multi-step reaction with 3 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 0.5 h

2: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 3 h / -20 - 0 °C

3: sodium periodate; ruthenium(III) trichloride hydrate / water; dichloromethane; acetonitrile / 2.75 h

With sodium periodate; trimethylsilyl trifluoromethanesulfonate; ruthenium(III) trichloride hydrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; water; acetonitrile;

DOI:10.1002/anie.201206797

upstream raw materials:

methyl 3,6-dideoxy-α-D-ribo-hexapyranoside

(2S,3R,5S,6R)-3,5-bis(benzyloxy)-2-methoxy-6-methyltetrahydro-2H-pyran

C₂₂H₂₄Cl₃NO₄

(3R,5S,6R)-3,5-bis(benzyloxy)-2-((R)-hex-5-en-2-yloxy)-6-methyltetrahydro-2H-pyran α-anomer