cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))]

Base Information

• Chemical Name: cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))]
• CAS No.: 915980-18-6
• Molecular Formula: C₅₉H₆₄P₂Pt
• Molecular Weight: 1030.18
• Mol file: 915980-18-6.mol

Synonyms:cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))]

Chemical Property of cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))]

There total 1 articles about cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)] (83095-83-4,14647-25-7) + 2,7-diethynyl-9,9-dioctyl-9H-fluorene (380600-93-1) → cis-[platinum(II)(1,2-bis(diphenylphosphanyl)ethane)(2,7-diethynyl-9,9-dioctylfluorene(-2H))] (915980-18-6)

Guidance literature:

With NEt₃; In dichloromethane; HCC(C13H6(C8H17)2)CCH (0.126 mmol), (PtCl2(P(C6H5)2)2C2H4) (0.126 mmol) and CuI mixed in NEt3/CH2Cl2 (1:10 v/v) at room temp., stirred overnightat room temp.; according to N.J.Long, C.K.Wong, A.J.P.White, Organometa llics, 2006, 25, 2525-2532; filtered, concd., soln. poured into MeOH, powder collected, washed (hexane), dried (under vac.);

DOI:10.1002/anie.200601651

upstream raw materials:

[platinum(II)dichloride(1,2-bis(diphenylphosphino)ethane)]

2,7-diethynyl-9,9-dioctyl-9H-fluorene