(3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

Base Information

Chemical Name:(3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal
CAS No.:782472-57-5
Molecular Formula:C₂₅H₃₄O₄
Molecular Weight:398.543
Hs Code.:

Synonyms:(3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

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Chemical Property of (3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

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Technology Process of (3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

There total 10 articles about (3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 782472-49-5
(R)-3-(4-Methoxy-benzyloxy)-octanal

: 782472-57-5
(3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

Guidance literature:: Multi-step reaction with 8 steps

1: 85 percent / benzene / 2 h / Heating

2: 79 percent / DIBAL-H / CH₂Cl₂ / 3 h / 20 °C

3: 83 percent / cumene hydroperoxide; (-)-DIPT; Ti(Oi-Pr)4 / CH₂Cl₂ / 3 h / -20 °C

4: 80 percent / NaAlH₂(OCH₂CH₂OMe)2 / tetrahydrofuran / 5 h / 0 °C

5: 84 percent / imidazole / CH₂Cl₂ / 6 h / 20 °C

6: 78 percent / NaH / tetrahydrofuran / 4 h / 0 - 20 °C

7: 89 percent / TBAF / CH₂Cl₂ / 10 h / 20 °C

8: 94 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 3 h / -78 °C

With 1H-imidazole; titanium(IV) isopropylate; oxalyl dichloride; Cumene hydroperoxide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; dichloromethane; benzene; 3: Sharpless asymmetric epoxidation / 8: Swern oxidation;
DOI:10.1016/j.tetlet.2004.08.052

Reference yield:

: 782472-51-9
(E)-(R)-5-(4-Methoxy-benzyloxy)-dec-2-en-1-ol

: 782472-57-5
(3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

Guidance literature:: Multi-step reaction with 6 steps

1: 83 percent / cumene hydroperoxide; (-)-DIPT; Ti(Oi-Pr)4 / CH₂Cl₂ / 3 h / -20 °C

2: 80 percent / NaAlH₂(OCH₂CH₂OMe)2 / tetrahydrofuran / 5 h / 0 °C

3: 84 percent / imidazole / CH₂Cl₂ / 6 h / 20 °C

4: 78 percent / NaH / tetrahydrofuran / 4 h / 0 - 20 °C

5: 89 percent / TBAF / CH₂Cl₂ / 10 h / 20 °C

6: 94 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 3 h / -78 °C

With 1H-imidazole; titanium(IV) isopropylate; oxalyl dichloride; Cumene hydroperoxide; tetrabutyl ammonium fluoride; sodium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; dichloromethane; 1: Sharpless asymmetric epoxidation / 6: Swern oxidation;
DOI:10.1016/j.tetlet.2004.08.052

Reference yield:

: 782472-48-4
(R)-3-(4-Methoxy-benzyloxy)-octan-1-ol

: 782472-57-5
(3R,5R)-3-Benzyloxy-5-(4-methoxy-benzyloxy)-decanal

Guidance literature:: Multi-step reaction with 9 steps

1: 88 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 3 h / -78 °C

2: 85 percent / benzene / 2 h / Heating

3: 79 percent / DIBAL-H / CH₂Cl₂ / 3 h / 20 °C

4: 83 percent / cumene hydroperoxide; (-)-DIPT; Ti(Oi-Pr)4 / CH₂Cl₂ / 3 h / -20 °C

5: 80 percent / NaAlH₂(OCH₂CH₂OMe)2 / tetrahydrofuran / 5 h / 0 °C

6: 84 percent / imidazole / CH₂Cl₂ / 6 h / 20 °C

7: 78 percent / NaH / tetrahydrofuran / 4 h / 0 - 20 °C

8: 89 percent / TBAF / CH₂Cl₂ / 10 h / 20 °C

9: 94 percent / (COCl)2; DMSO; Et₃N / CH₂Cl₂ / 3 h / -78 °C

With 1H-imidazole; titanium(IV) isopropylate; oxalyl dichloride; Cumene hydroperoxide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; D-(-)-diisopropyl tartrate; dimethyl sulfoxide; triethylamine; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; dichloromethane; benzene; 1: Swern oxidation / 4: Sharpless asymmetric epoxidation / 9: Swern oxidation;
DOI:10.1016/j.tetlet.2004.08.052