(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Base Information

Chemical Name:(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate
CAS No.:1213228-78-4
Molecular Formula:C₃₀H₁₇F₁₂O₄P
Molecular Weight:700.417
Hs Code.:

Synonyms:(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Suppliers and Price of (S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

There total 4 articles about (S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1213228-77-3
(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-diol

: 1213228-78-4
(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Guidance literature:: (S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-diol; With pyridine; trichlorophosphate; at 100 ℃; for 15h;

With water; In pyridine;
DOI:10.1021/ja2014955

Reference yield:

: (S)-2,2'-(bis(methoxymethoxy)-6,6'-dimethyl-1,1'-biphenyl-3,3'-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)

: 1213228-78-4
(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; barium hydroxide octahydrate / 1,4-dioxane; water / 40 h / Reflux

2: hydrogenchloride; water / 1,4-dioxane / 4 h / 65 °C

3: pyridine; trichlorophosphate / 15 h / 100 °C

With pyridine; hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; barium hydroxide octahydrate; water; trichlorophosphate; In 1,4-dioxane; water;
DOI:10.1021/ja2014955

Reference yield:

: 1213229-02-7
C₃₄H₂₆F₁₂O₄

: 1213228-78-4
(S)-6,6'-dimethyl-3,3'-bis(2,4-bistrifluoromethylphenyl)-1,1'-biphenyl-2,2'-yl phosphate

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogenchloride; water / 1,4-dioxane / 4 h / 65 °C

2: pyridine; trichlorophosphate / 15 h / 100 °C

With pyridine; hydrogenchloride; water; trichlorophosphate; In 1,4-dioxane;
DOI:10.1021/ja2014955