(-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate

Base Information

• Chemical Name: (-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate
• CAS No.: 98497-07-5
• Molecular Formula: C₁₉H₂₄O₃
• Molecular Weight: 300.398
• Mol file: 98497-07-5.mol

Synonyms:(-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate

Chemical Property of (-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate

There total 1 articles about (-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

(Z)-7-((1R,5S)-5-Hydroxy-cyclopent-2-enyl)-hept-5-enoic acid (98574-66-4) + benzyl alcohol (100-51-6,185532-71-2) → (-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate (98497-07-5)

Guidance literature:

With toluene-4-sulfonic acid; In benzene; Heating;

DOI:10.1016/S0040-4020(01)96437-3

Reference yield: 59.0%

(-)-benzyl <7-(5α-hydroxy-2-cyclopenten-α-yl)>-5(Z)-heptenoate (98497-07-5) → (-)-benzyl <7-(5α-hydroxy-2,3-α-epoxycyclopent-α-yl)>-5(Z)-heptenoate (98497-08-6)

Guidance literature:

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; In benzene; Heating;

DOI:10.1016/S0040-4020(01)96437-3

upstream raw materials:

(Z)-7-((1R,5S)-5-Hydroxy-cyclopent-2-enyl)-hept-5-enoic acid

benzyl alcohol

Downstream raw materials:

(-)-benzyl <7-(5α-hydroxy-2,3-α-epoxycyclopent-α-yl)>-5(Z)-heptenoate