3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate

Base Information

• Chemical Name: 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate
• CAS No.: 1398574-83-8
• Molecular Formula: C₄₉H₅₂O₁₀
• Molecular Weight: 800.946
• Mol file: 1398574-83-8.mol

Synonyms:3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate

Chemical Property of 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate

There total 11 articles about 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

4-((3-hydroxyphenoxy)carbonyl)phenyl 4-(heptyloxy)benzoate (1331828-93-3) + 4-[(4-[(1S)-1-methylheptyl]oxybenzoyl)oxy]benzoic acid (1398574-75-8) → 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate (1398574-83-8)

Guidance literature:

4-((3-hydroxyphenoxy)carbonyl)phenyl 4-(heptyloxy)benzoate; 4-[(4-[(1S)-1-methylheptyl]oxybenzoyl)oxy]benzoic acid; With dicyclohexyl-carbodiimide; In dichloromethane; for 0.166667h;

With dmap; In dichloromethane; at 20 ℃; for 16h;

DOI:10.1002/chem.201200057

Reference yield:

methyl 4-hydroxylbenzoate (99-76-3,156291-94-0) → 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate (1398574-83-8)

Guidance literature:

Multi-step reaction with 5 steps

1.1: triphenylphosphine / tetrahydrofuran / 0.25 h / 0 °C

1.2: 8 h / 0 - 20 °C

2.1: water; potassium hydroxide / tetrahydrofuran / 8 h / 80 °C

3.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 10 h / 20 °C

4.1: palladium 10% on activated carbon / ethanol; cyclohexene / 8 h / Reflux

5.1: dicyclohexyl-carbodiimide / dichloromethane / 0.17 h

5.2: 16 h / 20 °C

With dmap; palladium 10% on activated carbon; water; dicyclohexyl-carbodiimide; triphenylphosphine; potassium hydroxide; In tetrahydrofuran; ethanol; dichloromethane; cyclohexene; 1.1: Mitsunobu reaction / 1.2: Mitsunobu reaction;

DOI:10.1002/chem.201200057

Reference yield:

C29H32O5 → 3-[(4-{[4-(heptyloxy)benzoyl]oxy}benzoyl)oxy]phenyl 4-[(4-{[(1S)-1-methylheptyl]oxy}benzoyl)oxy] benzoate (1398574-83-8)

Guidance literature:

Multi-step reaction with 2 steps

1.1: palladium 10% on activated carbon / ethanol; cyclohexene / 8 h / Reflux

2.1: dicyclohexyl-carbodiimide / dichloromethane / 0.17 h

2.2: 16 h / 20 °C

With palladium 10% on activated carbon; dicyclohexyl-carbodiimide; In ethanol; dichloromethane; cyclohexene;

DOI:10.1002/chem.201200057

upstream raw materials:

4-((3-hydroxyphenoxy)carbonyl)phenyl 4-(heptyloxy)benzoate

4-[(4-[(1S)-1-methylheptyl]oxybenzoyl)oxy]benzoic acid

1-Bromoheptane

(R)-Octan-2-ol