2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone

Base Information

• Chemical Name: 2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone
• CAS No.: 82230-72-6
• Molecular Formula: C₂₆H₃₂N₂O₂S
• Molecular Weight: 436.618
• Mol file: 82230-72-6.mol

Synonyms:2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone

Chemical Property of 2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone

Chemical Property:

Purity/Quality:

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Technology Process of 2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone

There total 1 articles about 2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

trisylhydrazine (39085-59-1) + β-naphthaldehyde (66-99-9) → 2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone (82230-72-6)

Guidance literature:

In methanol; for 1h; Ambient temperature;

DOI:10.1055/s-1982-29821

Reference yield: 91.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone (82230-72-6) → trans-1-(β-Naphthyl)-2-phenylcyclopropan (53457-73-1)

Guidance literature:

With C₁₀₀H₈₄CoN₈O₁₆; caesium carbonate; In toluene; at 22 ℃; for 16h; stereoselective reaction; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/jacs.1c04655

Reference yield: 88.0%

2-Napthaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone (82230-72-6) + 1,1-bis(4-(trifluoromethyl)phenyl)siletane → (S)-2-(naphthalen-2-yl)-1,1-bis(4-(trifluoromethyl)phenyl)silolane

Guidance literature:

With allyl(cyclopentadiene)palladium(II); lithium tert-butoxide; (3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-bis-((R)-1-phenyl-ethyl)-amine; In 1,4-dioxane; toluene; at 0 ℃; for 24h; enantioselective reaction; Inert atmosphere;

DOI:10.1021/jacs.1c05879

upstream raw materials:

trisylhydrazine

β-naphthaldehyde

Downstream raw materials:

3,5-Dinitro-benzoic acid naphthalen-2-ylmethyl ester

trans-1-(β-Naphthyl)-2-phenylcyclopropan