(4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

Base Information

Chemical Name:(4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol
CAS No.:103498-96-0
Molecular Formula:C₂₄H₃₅NO₃S
Molecular Weight:417.613
Hs Code.:

Synonyms:(4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

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Technology Process of (4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

There total 13 articles about (4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 103498-95-9
(3RS,3aSR,4RS,6RS,7aSR)-4-methyl-N-<3-oxy>propyl>-3aH-inden-3a-yl>propyl>benzenesulfonamide

: 103498-96-0
(4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

Guidance literature:: With tetra(n-butyl)ammonium hydroxide; In toluene; for 1h; Heating;
DOI:10.1021/jo00268a015

Reference yield:

: 69060-78-2
2-(2-cyanoethyl)-5-methylcyclohex-2-en-1-one

: 103498-96-0
(4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

Guidance literature:: Multi-step reaction with 7 steps

1: 94 percent

2: 97 percent / CrO₃(C₅H₅N)2

3: 89 percent / 1.) NaOEt; 2.) NaOH / ethanol

4: 55 percent / C₆H₅CO₂Ag / methanol

5: LiAlH₄ / diethyl ether / -105 - 25 °C

6: 60 percent / pyridine

7: 60 percent / KH, 18-crown-6 / toluene / Heating

With sodium hydroxide; lithium aluminium tetrahydride; 18-crown-6 ether; sodium ethanolate; silver benzoate; potassium hydride; dipyridine chromium trioxide; In pyridine; methanol; diethyl ether; ethanol; toluene;
DOI:10.1021/ja00276a062

Reference yield:

: 103498-89-1,118892-12-9,118892-29-8
(2SR,4RS)-2-<2-(hydroxymethyl)-2-propenyl>-4-methyl-6-oxocyclohexanepropanenitrile

: 103498-96-0
(4SR,13RS)-5-methylene-17-<(4-methylphenyl)sulfonyl>-4,17-secoserratinan-13-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / CrO₃(C₅H₅N)2

2: 89 percent / 1.) NaOEt; 2.) NaOH / ethanol

3: 55 percent / C₆H₅CO₂Ag / methanol

4: LiAlH₄ / diethyl ether / -105 - 25 °C

5: 60 percent / pyridine

6: 60 percent / KH, 18-crown-6 / toluene / Heating

With sodium hydroxide; lithium aluminium tetrahydride; 18-crown-6 ether; sodium ethanolate; silver benzoate; potassium hydride; dipyridine chromium trioxide; In pyridine; methanol; diethyl ether; ethanol; toluene;
DOI:10.1021/ja00276a062