cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

Base Information

Chemical Name:cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate
CAS No.:1401427-56-2
Molecular Formula:C₁₉H₂₂O₅
Molecular Weight:330.381
Hs Code.:

Synonyms:cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

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Chemical Property of cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

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Technology Process of cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

There total 2 articles about cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 13057-19-7
Iodomethyl methyl ether

: 1401427-44-8
cyclohex-2-en-1-yl (1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl) carbonate

: 1401427-56-2
cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

Guidance literature:: cyclohex-2-en-1-yl (1-oxo-1,2,3,4-tetrahydronaphthalen-2-yl) carbonate; With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

Iodomethyl methyl ether; In tetrahydrofuran; for 0.5h; Inert atmosphere;
DOI:10.1002/anie.201203663

Reference yield:

: 141037-04-9
cyclohex-2-en-1-yl 1H-imidazole-1-carboxylate

: 1401427-56-2
cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hexamethyldisilazane / 1,2-dimethoxyethane / 1 h / -78 °C / Inert atmosphere

1.2: 2.17 h / -78 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1.5 h / 20 °C

3.1: boron trifluoride diethyl etherate / diethyl ether / -78 °C / Inert atmosphere

4.1: sodium hexamethyldisilazane / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

4.2: 0.5 h / Inert atmosphere

With boron trifluoride diethyl etherate; sodium hexamethyldisilazane; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; dichloromethane;
DOI:10.1002/anie.201203663

Reference yield: 50.0%

: 1401427-56-2
cyclohex-2-en-1-yl (2-(methoxymethoxy)-3,4-dihydronaphthalen-1-yl) carbonate

: 1401427-68-6
2-(cyclohex-2-en-1-yl)-2-(methoxymethoxy)-3,4-dihydronaphthalen-1(2H)-one

Guidance literature:: With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; (R,R)-ANDEN-phenyl Trost ligand; In tetrahydrofuran; at 20 ℃; for 16h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201203663