3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole

Base Information

• Chemical Name: 3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole
• CAS No.: 1401560-34-6
• Molecular Formula: C₂₉H₂₀ClN
• Molecular Weight: 417.938
• Mol file: 1401560-34-6.mol

Synonyms:3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole

Chemical Property of 3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole

There total 2 articles about 3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

2-[2-(4-chlorophenyl)ethynyl]-N,N-dimethylaniline (62167-06-0) + diphenyl acetylene (501-65-5) → 3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole (1401560-34-6)

Guidance literature:

With tetrabutylammomium bromide; oxygen; copper diacetate; sodium acetate; palladium diacetate; trimethylpyruvic acid; In N,N-dimethyl acetamide; at 90 ℃; for 12h; under 760.051 Torr; regioselective reaction;

DOI:10.1021/jo301741j

Reference yield: 61.0%

2-(4-chlorophenyl)-1-methyl-2-phenyl-1H-indole (5905-11-3) + diphenyl acetylene (501-65-5) → 3-chloro-11-methyl-5,6-diphenyl-11H-benzo[a]carbazole (1401560-34-6)

Guidance literature:

With C₃₆H₃₆N₃O₃PPd⁽²⁺⁾*2CF₃O₃S^(1-); tetrabutylammomium bromide; copper diacetate; In N,N-dimethyl acetamide; at 90 ℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1002/ejoc.201500417

upstream raw materials:

2-[2-(4-chlorophenyl)ethynyl]-N,N-dimethylaniline

diphenyl acetylene

2-(4-chlorophenyl)-1-methyl-2-phenyl-1H-indole