1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C⁶⁰-I^h)[5,6]fullerene

Base Information

• Chemical Name: 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C⁶⁰-I^h)[5,6]fullerene
• CAS No.: 745075-50-7
• Molecular Formula: C₉₆H₄₁N
• Molecular Weight: 1208.39

Synonyms:1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C⁶⁰-I^h)[5,6]fullerene

Chemical Property of 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C⁶⁰-I^h)[5,6]fullerene

Chemical Property:

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Technology Process of 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C⁶⁰-I^h)[5,6]fullerene

There total 1 articles about 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C⁶⁰-I^h)[5,6]fullerene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenylmagnesium bromide + 1-cyano-6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro(C60-Ih)[5,6]fullerene (451472-18-7) → 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C60-Ih)[5,6]fullerene (745075-50-7) + 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,60-dodecahydro(C60-I60)[5,6]fullerene + 1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,56-dodecahydro(C60-Ih)[5,6]fullerene (503835-64-1)

Guidance literature:

With 1,3-dimethyl-2-imidazolidinone; copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; 1,2-dichloro-benzene; at 23 ℃; for 24h; Title compound not separated from byproducts.;

DOI:10.1021/ja029915z

Reference yield: 57.0%

1-cyano-6,9,12,15,18-pentamethyl-43,46,49,52,55-pentaphenyl-1,6,9,12,15,18,43,46,49,52,55,57-dodecahydro(C60-Ih)[5,6]fullerene (745075-50-7) + bis(η3-allyl-μ-chloropalladium(II)) → [Pd(π-allyl)(C60(CN)Me5Ph5)] (745075-38-1)

Guidance literature:

With (t-butyl)OK; In tetrahydrofuran; (N2 or Ar); using Schlenk techniques; addn. of THF soln. of t-BuOK (1.1 equiv.) to soln. of C60(CN)Me5Ph5H in THF; addn. of (Pd(C3H5)Cl)2; stirring at 26°C for 10 min, quenching with satd. aq. NH4Cl; dilution with toluene, collection of org. layer; drying over MgSO4; concn. in vac., HPLC (toluene/hexane, 3:7); evapn.; addn. of MeOH; pptn., recrystn. from a two-layered soln. of chlorobenzene and ethanol;

DOI:10.1021/ja048683w

upstream raw materials:

1-cyano-6,9,12,15,18-pentamethyl-1,6,9,12,15,18-hexahydro(C⁶⁰-I^h)[5,6]fullerene

Downstream raw materials:

[Pd(π-allyl)(C60(CN)Me5Ph5)]

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