methyl 4-(4-oxopentan-2-yl)benzoate

Base Information

• Chemical Name: methyl 4-(4-oxopentan-2-yl)benzoate
• CAS No.: 50793-51-6
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.268
• Mol file: 50793-51-6.mol

Synonyms:methyl 4-(4-oxopentan-2-yl)benzoate

Chemical Property of methyl 4-(4-oxopentan-2-yl)benzoate

Chemical Property:

Purity/Quality:

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Technology Process of methyl 4-(4-oxopentan-2-yl)benzoate

There total 4 articles about methyl 4-(4-oxopentan-2-yl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

methyl 4-(4-(((1-methoxy-2-methyl-1-oxopropan-2-yl)oxy)imino)pentan-2-yl)benzoate → methyl 4-(4-oxopentan-2-yl)benzoate (50793-51-6)

Guidance literature:

With hydrogenchloride; water; In 1,4-dioxane; at 100 ℃; for 20h; Sealed tube;

DOI:10.1021/jacs.7b09761

Reference yield: 74.0%

methyl 4-iodobenzoate (619-44-3) + 2-Pentanone (107-87-9) → methyl 4-(4-oxopentan-2-yl)benzoate (50793-51-6)

Guidance literature:

With (+/-)-α-benzyl-β-aminopropionic acid; silver(I) acetate; palladium diacetate; silver trifluoroacetate; acetic acid; at 120 ℃; for 72h;

DOI:10.1021/acscatal.7b02905

Reference yield: 62.0%

Methyl 4-chlorobenzoate (1126-46-1) + 3-penten-2-one (625-33-2) → methyl 4-(4-oxopentan-2-yl)benzoate (50793-51-6)

Guidance literature:

Methyl 4-chlorobenzoate; With tetrabutylammonium tetrafluoroborate; zinc(II) chloride; In pyridine; acetonitrile; Electrochemical reaction;

3-penten-2-one; cobalt 2,2'-bipyridine dibromide; In pyridine; acetonitrile; at 50 ℃; for 15h;

DOI:10.1055/s-2002-34250

upstream raw materials:

Methyl 4-chlorobenzoate

3-penten-2-one

methyl 4-iodobenzoate

2-Pentanone