Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate)

Base Information

• Chemical Name: Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate)
• CAS No.: 75213-31-9
• Molecular Formula: C₇₂H₄₈N₆Ru*2ClO₄
• Molecular Weight: 1297.18
• DSSTox Substance ID: DTXSID70475125
• Mol file: 75213-31-9.mol

Synonyms:75213-31-9;Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate);4,7-diphenyl-1,10-phenanthroline;ruthenium(2+);diperchlorate;MFCD03093709;TRIS(4 7-DIPHENYL-1 10-PHENANTHROLINE)RU;DTXSID70475125;F87725;4,7-diphenyl-1,10-phenanthroline ruthenium(+2) cation diperchlorate;Tris(4,7-diphenyl-1,10-phenanthroline) ruthenium (II) perchlorate

Chemical Property of Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate)

Chemical Property:

• Vapor Pressure: 2.63E-11mmHg at 25°C
• Boiling Point: 543.1°C at 760 mmHg
• Flash Point: 242.1°C
• PSA: 225.88000
• LogP: 18.77960
• Storage Temp.: Hygroscopic, -20°C Freezer, Under inert atmosphere
• Solubility.: Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly), Methanol (Sligh
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 6
• Exact Mass: 1296.195408
• Heavy Atom Count: 89
• Complexity: 505

Purity/Quality:

99% ^*data from raw suppliers

Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II)bis(perchlorate) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.C1=CC=C(C=C1)C2=C3C=CC4=C(C=CN=C4C3=NC=C2)C5=CC=CC=C5.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Ru+2]
• Uses: Tetramethylrhodamine isothiocyanate mixed isomers is an amino-reactive labeling reagent.

Technology Process of Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate)

There total 2 articles about Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) bis(perchlorate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

bathophenanthroline (1662-01-7) + potassium perchlorate + ruthenium(III)chloride (10049-08-8,63767-78-2) → tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) perchlorate (75213-31-9)

Guidance literature:

In ethanol; water; (N2), mixed in methanol, refluxed for 48 h, evapd.(vac.), recrystd.(aq.NaClO4); elem. anal.;

DOI:10.1021/jp0369645

Reference yield:

potassium aquapentachlororuthenate(III) + bathophenanthroline (1662-01-7) + sodium perchlorate → tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) perchlorate (75213-31-9)

Guidance literature:

With hypophosphorous acid; In ethanol; water; refluxing (12 h), reducing (hypophosphorous acid), refluxing (2 h), pptn. on NaClO4 addn.;

DOI:10.1021/jp952181a

Reference yield:

tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) perchlorate (75213-31-9) + sodium antimonyl tartrate + sodium perchlorate → Ru(C12H6N2(C6H5)2)3(2+)*2ClO4(1-)=[Ru(C12H6N2(C6H5)2)3](ClO4)2

Guidance literature:

In ethanol; water; pptn. on sodium antimonyl tartrate addn., filtn., anion of the salt converted to perchlorate by use of anion exchange resin, pptn. on NaClO4 addn. to filtrate;

DOI:10.1021/jp952181a

upstream raw materials:

bathophenanthroline

ruthenium(III)chloride