(3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

Base Information

Chemical Name:(3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol
CAS No.:1335101-39-7
Molecular Formula:C₂₄H₃₀O₄
Molecular Weight:382.5
Hs Code.:

Synonyms:(3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

Suppliers and Price of (3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

Chemical Property:

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Technology Process of (3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

There total 12 articles about (3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 1335101-49-9
(1E,3S,4S,7S,8S,9E)-4,7-bis(benzyloxy)-1,10-ditosyldeca-1,9-diene-3,8-diol

: 1335101-39-7
(3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

Guidance literature:: With ethanol; magnesium; mercury dichloride; at 0 - 20 ℃; for 4h; Inert atmosphere;
DOI:10.1016/j.tet.2011.07.079

Reference yield:

: 1335101-42-2
tert-butyldimethyl((2S,3E,5E)-(1Ss)-(p-tolylsulfinyl)hepta-3,5-dien-2-yloxy)silane

: 1335101-39-7
(3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

Guidance literature:: Multi-step reaction with 9 steps

1.1: water / toluene / 0.08 h / 20 °C

1.2: 2 h / 20 °C

2.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 12 h / 20 °C / Inert atmosphere

3.1: camphor-10-sulfonic acid / dichloromethane / 4 h / Inert atmosphere

4.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 96 h / Inert atmosphere; Reflux

5.1: platinum oxide on carbon; hydrogen / methanol; benzene / 24 h / 20 °C / 7500.75 Torr / Inert atmosphere

6.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

7.1: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0 - 20 °C / Inert atmosphere

8.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.58 h / 0 - 20 °C / Inert atmosphere

9.1: ethanol; magnesium; mercury dichloride / 4 h / 0 - 20 °C / Inert atmosphere

With Hoveyda-Grubbs catalyst second generation; ethanol; trifluorormethanesulfonic acid; platinum oxide on carbon; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; water; hydrogen; magnesium; acetic acid; 3-chloro-benzenecarboperoxoic acid; mercury dichloride; In tetrahydrofuran; methanol; dichloromethane; cyclohexane; toluene; benzene;
DOI:10.1016/j.tet.2011.07.079

Reference yield:

: 1335101-40-0
(S,3E,5E)-1-((S)-p-tolylsulfinyl)hepta-3,5-dien-2-ol

: 1335101-39-7
(3S,4S,7S,8S)-4,7-bis(benzyloxy)deca-1,9-diene-3,8-diol

Guidance literature:: Multi-step reaction with 10 steps

1.1: 1H-imidazole / dichloromethane / 0 - 20 °C / Inert atmosphere

2.1: water / toluene / 0.08 h / 20 °C

2.2: 2 h / 20 °C

3.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran / 12 h / 20 °C / Inert atmosphere

4.1: camphor-10-sulfonic acid / dichloromethane / 4 h / Inert atmosphere

5.1: Hoveyda-Grubbs catalyst second generation / dichloromethane / 96 h / Inert atmosphere; Reflux

6.1: platinum oxide on carbon; hydrogen / methanol; benzene / 24 h / 20 °C / 7500.75 Torr / Inert atmosphere

7.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

8.1: trifluorormethanesulfonic acid / dichloromethane; cyclohexane / 0 - 20 °C / Inert atmosphere

9.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.58 h / 0 - 20 °C / Inert atmosphere

10.1: ethanol; magnesium; mercury dichloride / 4 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; Hoveyda-Grubbs catalyst second generation; ethanol; trifluorormethanesulfonic acid; platinum oxide on carbon; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; water; hydrogen; magnesium; acetic acid; 3-chloro-benzenecarboperoxoic acid; mercury dichloride; In tetrahydrofuran; methanol; dichloromethane; cyclohexane; toluene; benzene;
DOI:10.1016/j.tet.2011.07.079