[(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅))Re(O)Cl]

Base Information

• Chemical Name: [(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅))Re(O)Cl]
• CAS No.: 443879-07-0
• Molecular Formula: C₂₅H₁₅ClF₁₅N₄ORe
• Molecular Weight: 894.056
• Mol file: 443879-07-0.mol

Synonyms:[(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅))Re(O)Cl]

Chemical Property of [(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅))Re(O)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅))Re(O)Cl]

There total 1 articles about [(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅))Re(O)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[ReOCl3(PPh3)2] + ((C6F5)NHCH2CH2)2NCH2CH2CH2NH(C6F5) (443879-29-6) → [(((C6F5)NCH2CH2)2NCH2CH2CH2NH(C6F5))Re(O)Cl] (443879-07-0)

Guidance literature:

With NEt₃; In tetrahydrofuran; byproducts: NEt3HCl, PPh3; (N2); standard Schlenk technique; soln. of ligand and NEt3 in THF was added to suspn. of Re complex in THF at room temp.; mixt. was stirred for 5 h; concd.; cooled to -10°C; filtered through Celite; solvent removed(vac.); washed (Et2O); recrystd. (CH3CN); elem. anal.;

DOI:10.1021/ic025572u

Reference yield: 95.0%

[(((C6F5)NCH2CH2)2NCH2CH2CH2NH(C6F5))Re(O)Cl] (443879-07-0) + toluene (108-88-3,15644-74-3,16713-13-6) → [(((C6F5)NCH2CH2)2NCH2CH2CH2NH(C6F5))ClReOReBrCl(((C6F5)NCH2CH2)2NCH2CH2CH2NH(C6F5))]*2CH3C6H5

Guidance literature:

With TaCH(CPhMe₂)Br₃(THF)2; In toluene; (N2); standard Schlenk technique; soln. of Ta complex (1 equiv.) in toluene was slowly added by cannula to suspn. of Re complex in toluene at -20°C; filtered at low temp.; dried (vac.); elem. anal.;

DOI:10.1021/ic025572u

Reference yield: 70.0%

[(((C6F5)NCH2CH2)2NCH2CH2CH2NH(C6F5))Re(O)Cl] (443879-07-0) → [(((C6F5)NCH2CH2)2NCH2CH2CH2N(C6F5))ReCl] (443879-15-0)

Guidance literature:

With TaCH(CPhMe₂)Cl₃(THF)2; In toluene; (N2); standard Schlenk technique; soln. of Ta complex (2.1 equiv.) in toluene was slowly added by cannula to suspn. of Re complex in toluene at -20°C; mixt. was stirred at room temp. for 2 h; concd. (vac.); stored at -20°C; filtered; washed (cold toluene); dried (vac.); elem. anal.;

DOI:10.1021/ic025572u

upstream raw materials:

((C₆F₅)NHCH₂CH₂)2NCH₂CH₂CH₂NH(C₆F₅)

Downstream raw materials:

[(((C₆F₅)NCH₂CH₂)2NCH₂CH₂CH₂N(C₆F₅))ReCl]