C₅₃H₈₁NO₁₄Si₂

Base Information

Chemical Name:C₅₃H₈₁NO₁₄Si₂
CAS No.:1393595-35-1
Molecular Formula:C₅₃H₈₁NO₁₄Si₂
Molecular Weight:1012.4
Hs Code.:

C<sub>53</sub>H<sub>81</sub>NO<sub>14</sub>Si<sub>2</sub>

Synonyms:C₅₃H₈₁NO₁₄Si₂

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Chemical Property of C₅₃H₈₁NO₁₄Si₂

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Technology Process of C₅₃H₈₁NO₁₄Si₂

There total 27 articles about C₅₃H₈₁NO₁₄Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 21852-32-4
4-bromomethyl-1,2-dimethoxybenzene

: 1393595-35-1
C₅₃H₈₁NO₁₄Si₂

Guidance literature:: Multi-step reaction with 6 steps

1.1: potassium carbonate / acetone / 24 h / Inert atmosphere

2.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.33 h / -78 °C / Inert atmosphere

3.1: phenylborondichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere

3.2: -78 - 0 °C / Inert atmosphere

3.3: 4.25 h / -78 °C / Inert atmosphere

4.1: diethyl methoxy borane / methanol; tetrahydrofuran / 0.42 h / -78 °C / Inert atmosphere

4.2: -78 - 0 °C / Inert atmosphere

4.3: 35 h / 20 °C / Inert atmosphere

5.1: N-ethyl-N,N-diisopropylamine / acetone / 1 h / 0 °C / Inert atmosphere

5.2: 0.33 h / 0 °C / Inert atmosphere

6.1: toluene / 0.75 h / 80 °C / Inert atmosphere; Reflux

6.2: 5 h / 80 °C / Inert atmosphere; Reflux

With diethyl methoxy borane; phenylborondichloride; diisobutylaluminium hydride; potassium carbonate; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; hexane; dichloromethane; acetone; toluene; 6.2: |Curtius Rearrangement;
DOI:10.1021/jo400260m

Reference yield:

: C₂₇H₃₆O₅

: 1393595-35-1
C₅₃H₈₁NO₁₄Si₂

Guidance literature:: Multi-step reaction with 19 steps

1.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.08 h / -78 °C / Inert atmosphere

2.1: L-(+)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / -20 °C / Inert atmosphere; Molecular sieve

3.1: dimethyl sulfoxide; sulfur trioxide pyridine complex; triethylamine / dichloromethane / 1.5 h / 0 °C / Inert atmosphere

4.1: dichloromethane / 0.02 h / 0 °C / Inert atmosphere

5.1: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; tributylphosphine; formic acid; triethylamine / 1,4-dioxane / 9.5 h / 20 °C / Inert atmosphere

6.1: 2,6-dimethylpyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

7.1: diisobutylaluminium hydride / dichloromethane; hexane / 0.12 h / -78 °C / Inert atmosphere

8.1: D-(-)-diisopropyl tartrate; titanium(IV) isopropylate; tert.-butylhydroperoxide / dichloromethane; decane / 4 h / -20 °C / Inert atmosphere; Molecular sieve

9.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hypochlorite; sodium chlorite / acetonitrile / 1.5 h / pH 7 / Inert atmosphere

10.1: diethyl ether / 0 °C / Inert atmosphere

11.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 0.77 h / 0 °C / pH 7 / Inert atmosphere

12.1: camphor-10-sulfonic acid / dichloromethane / 5 h / 20 °C / Inert atmosphere

13.1: sodium hydride / tetrahydrofuran; mineral oil / 0.33 h / 0 °C / Inert atmosphere

13.2: 1.5 h / 0 - 20 °C / Inert atmosphere

14.1: palladium 10% on activated carbon; hydrogen / ethyl acetate / 5 h / 20 °C / Inert atmosphere

15.1: Dess-Martin periodane; sodium hydrogencarbonate / dichloromethane / 1 h / 0 °C / Inert atmosphere

16.1: phenylborondichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere

16.2: -78 - 0 °C / Inert atmosphere

16.3: 4.25 h / -78 °C / Inert atmosphere

17.1: diethyl methoxy borane / methanol; tetrahydrofuran / 0.42 h / -78 °C / Inert atmosphere

17.2: -78 - 0 °C / Inert atmosphere

17.3: 35 h / 20 °C / Inert atmosphere

18.1: N-ethyl-N,N-diisopropylamine / acetone / 1 h / 0 °C / Inert atmosphere

18.2: 0.33 h / 0 °C / Inert atmosphere

19.1: toluene / 0.75 h / 80 °C / Inert atmosphere; Reflux

19.2: 5 h / 80 °C / Inert atmosphere; Reflux

With 2,6-dimethylpyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium hypochlorite; sodium chlorite; formic acid; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; L-(+)-diisopropyl tartrate; tributylphosphine; palladium 10% on activated carbon; camphor-10-sulfonic acid; diethyl methoxy borane; phenylborondichloride; hydrogen; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; D-(-)-diisopropyl tartrate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; N-ethyl-N,N-diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; decane; hexane; dichloromethane; ethyl acetate; acetone; toluene; acetonitrile; mineral oil; 2.1: |Sharpless Asymmetric Epoxidation / 3.1: |Parikh-Doering Oxidation / 4.1: |Horner-Wadsworth-Emmons Olefination / 8.1: |Sharpless Asymmetric Epoxidation / 19.2: |Curtius Rearrangement;
DOI:10.1021/jo400260m

Reference yield:

: C₂₀H₃₈O₆Si

: 1393595-35-1
C₅₃H₈₁NO₁₄Si₂

Guidance literature:: Multi-step reaction with 6 steps

1.1: camphor-10-sulfonic acid / dichloromethane / 2 h / Inert atmosphere

2.1: dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere

3.1: phenylborondichloride / dichloromethane / 0.33 h / -78 °C / Inert atmosphere

3.2: -78 - 0 °C / Inert atmosphere

3.3: 4.25 h / -78 °C / Inert atmosphere

4.1: diethyl methoxy borane / methanol; tetrahydrofuran / 0.42 h / -78 °C / Inert atmosphere

4.2: -78 - 0 °C / Inert atmosphere

4.3: 35 h / 20 °C / Inert atmosphere

5.1: N-ethyl-N,N-diisopropylamine / acetone / 1 h / 0 °C / Inert atmosphere

5.2: 0.33 h / 0 °C / Inert atmosphere

6.1: toluene / 0.75 h / 80 °C / Inert atmosphere; Reflux

6.2: 5 h / 80 °C / Inert atmosphere; Reflux

With camphor-10-sulfonic acid; diethyl methoxy borane; phenylborondichloride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; dichloromethane; acetone; toluene; 6.2: |Curtius Rearrangement;
DOI:10.1021/jo400260m