trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

Base Information

Chemical Name:trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium
CAS No.:221037-00-9
Molecular Formula:C₃₂H₅₂ClOP₂Rh
Molecular Weight:653.07
Hs Code.:

Synonyms:trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

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Chemical Property of trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

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Technology Process of trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

There total 2 articles about trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: di-μ-chloro-bis[bis(cyclo-octene)rhodium]

: 525-06-4
diphenyl ketene

: 6476-36-4
tris(1-methylethyl)phosphine

: 221037-00-9
trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

Guidance literature:: 2 equiv. of Ph2CCO and 4 equiv. of P(i-Pr)3;

Reference yield: 87.0%

: bis(triisopropylphosphine)rhodium chloride dimer

: 525-06-4
diphenyl ketene

: 221037-00-9
trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

Guidance literature:: In benzene; addn. of diphenylketene to soln. of Rh complex, stirring (room temp., 5 min); removement of solvent (vacuum), washing (pentane), drying;
DOI:10.1002/(SICI)1521-3773(19990115)38:1/2<156::AID-ANIE156>3.0.CO;2-I

Reference yield: 86.0%

: 12128-56-2
potassium indenyl

: 221037-00-9
trans-chlorobis(triisopropylmethylphosphine)(η2-C,O-diphenylketene)rhodium

: 221037-02-1,221037-01-0
Rh(indenyl)(P(C₃H₇)3)(eta.⁽²⁾(C,C)-diphenylketene)

Guidance literature:: With AgPF₆; In tetrahydrofuran; acetone; addn. of acetone soln. of AgPF6 to acetone soln. of Rh complex, stirring(room temp., 5 min), filtration, evapn. (vacuum), addn. of C9H7K to THF soln. of Rh complex, stirring (30 min); removement of solvent, extn. (pentane), filtration, concn., crystn. (0°C, 12 h), washing (pentane), drying (vacuum);
DOI:10.1002/(SICI)1521-3773(19990115)38:1/2<156::AID-ANIE156>3.0.CO;2-I