4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

Base Information

Chemical Name:4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside
CAS No.:321156-80-3
Molecular Formula:C₁₆H₁₇NO₇S₂
Molecular Weight:399.445
Hs Code.:

Synonyms:4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

Suppliers and Price of 4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

There total 9 articles about 4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1849-36-1
para-nitrobenzenethiol

: 209112-42-5
1,2,5-tri-O-acetyl-3,6-anhydro-3-thio-D-glucofuranose

: 4-nitrophenyl 3,5-di-O-acetyl-2,6-anhydro-1,2-dithio-D-altrofuranoside

: 321156-80-3
4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

: 4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-α-D-glucofuranoside

Guidance literature:: With boron trifluoride diethyl etherate; In 1,2-dichloro-ethane; at 20 ℃; for 24h;
DOI:10.1016/S0008-6215(00)00218-4

Reference yield:

: 28251-82-3
3,6-anhydro-1,2-O-isopropylidene-3-thio-α-D-glucofuranose

: 321156-80-3
4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / pyridine

2: HCl / acetic acid / 0.17 h / 100 °C

3: 4.4 g / 0.17 h / 100 °C

4: 68 percent / BF₃*Et₂O / 1,2-dichloro-ethane / 24 h / 20 °C

With hydrogenchloride; boron trifluoride diethyl etherate; In pyridine; acetic acid; 1,2-dichloro-ethane;
DOI:10.1016/S0008-6215(00)00218-4

Reference yield:

: 14728-80-4
1,2:5,6-di-O-isopropylidene-3-O-(methylsulphonyl)-α-D-allofuranose

: 321156-80-3
4-nitrophenyl 2,5-di-O-acetyl-3,6-anhydro-1,3-dithio-β-D-glucofuranoside

Guidance literature:: Multi-step reaction with 9 steps

1: 85.7 percent / HCl / methanol / 0.5 h / 50 °C

2: pyridine / 1 h

3: 22 g / pyridine / 8 h / 20 °C

4: 90 percent / dimethylformamide / 1 h / 100 °C

5: 82 percent / NaOMe / methanol; CH₂Cl₂ / 0.5 h / 20 °C

6: 93 percent / pyridine

7: HCl / acetic acid / 0.17 h / 100 °C

8: 4.4 g / 0.17 h / 100 °C

9: 68 percent / BF₃*Et₂O / 1,2-dichloro-ethane / 24 h / 20 °C

With hydrogenchloride; boron trifluoride diethyl etherate; sodium methylate; In pyridine; methanol; dichloromethane; acetic acid; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1016/S0008-6215(00)00218-4