Flurochloridone

Base Information

• Chemical Name: Flurochloridone
• CAS No.: 61213-25-0
• Deprecated CAS: 89286-81-7
• Molecular Formula: C12H10Cl2F3NO
• Molecular Weight: 312.119
• Hs Code.: 2933990016
• European Community (EC) Number: 262-661-3
• DSSTox Substance ID: DTXSID0041987
• Nikkaji Number: J265.193I
• Wikidata: Q18624139
• Metabolomics Workbench ID: 67988
• ChEMBL ID: CHEMBL2272973
• Mol file: 61213-25-0.mol

Synonyms:3-chloro-4-(chloromethyl)-1-(3-(trifluoromethyl)phenyl)-2-pyrrolidinone;fluorochloridone;flurochloridone;raiser

Chemical Property of Flurochloridone

Chemical Property:

• Vapor Pressure: 2.02E-08mmHg at 25°C
• Melting Point: 80 - 81oC
• Refractive Index: 1.536
• Boiling Point: 453.7 °C at 760 mmHg
• PKA: -3.59±0.60(Predicted)
• Flash Point: 228.2 °C
• PSA: 20.31000
• Density: 1.46 g/cm³
• LogP: 3.57940
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 311.0091538
• Heavy Atom Count: 19
• Complexity: 350

Purity/Quality:

99% ^*data from raw suppliers

Flurochloridon ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-27-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(C(C(=O)N1C2=CC=CC(=C2)C(F)(F)F)Cl)CCl
• Uses: Flurochloridone (FLC) is a monophenyl pyrrolidinone selective herbicide that can be used in herbicidal composition to control weed in crop fields. It is commonly used to inhibit weeds that occur during the growth of crop plants, such as grains, sunflowers, and potatoes.

Technology Process of Flurochloridone

There total 5 articles about Flurochloridone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.6%

N-allyl-N-dichloroacetyl-m-trifluoromethylaniline (61219-95-2) → fluorochloridone (61213-25-0)

Guidance literature:

With [2,2]bipyridinyl; copper(l) chloride; In 1,2-dichloro-ethane; at 80 ℃; for 3h; Temperature;

Reference yield:

→ fluorochloridone (61213-25-0)

Guidance literature:

Reference yield:

→ trans-1-m-trifluoromethylphenyl-3-chloro-4-chloromethyl-2-pyrrolidone (61213-25-0,61213-59-0,61213-60-3)

Guidance literature:

upstream raw materials:

N-allyl-N-dichloroacetyl-m-trifluoromethylaniline

Downstream raw materials:

4-chloromethyl-1-(3-trifluoromethyl-phenyl)-2-pyrrolidone

Refernces

• 1、 -. "Process for improving cyclization synthesis yield of fluorochloridone". Paragraph 0012-0018. . Retrieved 2018/04/21.
• 2、 -. "Synergistic herbicidal compositions". . . Retrieved 2008/06/13.