allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

Base Information

Chemical Name:allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside
CAS No.:181115-83-3
Molecular Formula:C₆₃H₇₄O₁₇
Molecular Weight:1103.27
Hs Code.:

Synonyms:allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

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Chemical Property of allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

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Technology Process of allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

There total 10 articles about allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: (4aR,6R,7R,8S,8aR)-6-[(2R,3R,4S,5R,6R)-6-Allyloxy-4,5-bis-(4-methoxy-benzyloxy)-2-(4-methoxy-benzyloxymethyl)-tetrahydro-pyran-3-yloxy]-7,8-bis-(4-methoxy-benzyloxy)-2-(4-methoxy-phenyl)-hexahydro-pyrano[3,2-d][1,3]dioxine

: 181115-83-3
allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

Guidance literature:: With sodium cyanoborohydride; trifluoroacetic acid; In N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(96)01021-0

Reference yield: 11.0%

: 181115-77-5
allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3-di-O-4-methoxybenzyl-4,6-O-4-methoxybenzylidene-α-D-glucopyranosyl)-β-D-glucopyranoside

: 181115-83-3
allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

: allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,4-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

Guidance literature:: With 3 Angstroems MS; sodium cyanoborohydride; In N,N-dimethyl-formamide; trifluoroacetic acid; for 16h; Ambient temperature;
DOI:10.1021/jo9807823

Reference yield:

: 97777-13-4
allyl O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-(1<*>4)-2,3,6-tri-O-acetyl-β-D-gluco-pyranoside

: 181115-83-3
allyl 2,3,6-tri-O-4-methoxybenzyl-4-O-(2,3,6-tri-O-4-methoxybenzyl-α-D-glucopyranosyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: NaOMe / methanol / 25 °C

2: 60 percent / p-TsOH / dimethylformamide / 2 h / 60 °C

3: 89 percent / NaH / dimethylformamide / 16 h / 25 °C

4: 74 percent / NaCNBH₃, 3 Angstroems MS / trifluoroacetic acid; dimethylformamide / 16 h / Ambient temperature

With 3 Angstroems MS; sodium methylate; sodium hydride; sodium cyanoborohydride; toluene-4-sulfonic acid; In methanol; N,N-dimethyl-formamide; trifluoroacetic acid;
DOI:10.1021/jo9807823